Crystal Structure and Infrared Spectra of di-μ-Chlorobis[(di-Isopropyl Phosphite)-(di-Isopropyl Phosphito) (Carbonyl) Chlororhodium(III)] ([RhCl2(CO){P(OC3H7)2O}2H]2) Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
||||
---|---|---|---|---|---|
Output data | Year: 1982, Volume: 23, Number: 3, Pages: 389-394 Pages count : 6 DOI: 10.1007/BF00753475 | ||||
Tags | Physical Chemistry; Crystal Structure; Inorganic Chemistry; Carbonyl; Infrared Spectrum | ||||
Authors |
|
||||
Affiliations |
|
Abstract:
The crystal structure of the rhodium complex [Rh III CI2(CO)[PO[iso-C3HT)O]2}{POH 9 [isoC3HT)O]2}]2 has been determined (a = 10.247(2), b = 14.193(3), c = 16.334(4) A, beta = 98.16 o , space group P21/n, Z=2, dmeas= 1.436, dcalc=1.505 g/cm3). The coordination polyhedra of rhodium have a common edge, forming a dimer with bridging chloride atoms. A characteristic feature of the structure is the short intramolecular hydrogen bond O...H...O 2.459 A between the phosphite ligand oxygen atoms not joined to isopropyl groups. The existence of this bond has been confirmed by the infrared spectra. On the basis of the structural data for the compound studied, the bands
in its infrared spectrum and the infrared spectra of various complexes of Rh(I) and Rh(III) have been identified.
Cite:
Glinskaya L.A.
, Yurchenko E.N.
, Solodovnikov S.F.
, Gracheva L.S.
, Klevtsova R.F.
Crystal Structure and Infrared Spectra of di-μ-Chlorobis[(di-Isopropyl Phosphite)-(di-Isopropyl Phosphito) (Carbonyl) Chlororhodium(III)] ([RhCl2(CO){P(OC3H7)2O}2H]2)
Journal of Structural Chemistry. 1982. V.23. N3. P.389-394. DOI: 10.1007/BF00753475 WOS Scopus РИНЦ
Crystal Structure and Infrared Spectra of di-μ-Chlorobis[(di-Isopropyl Phosphite)-(di-Isopropyl Phosphito) (Carbonyl) Chlororhodium(III)] ([RhCl2(CO){P(OC3H7)2O}2H]2)
Journal of Structural Chemistry. 1982. V.23. N3. P.389-394. DOI: 10.1007/BF00753475 WOS Scopus РИНЦ
Original:
Глинская Л.А.
, Юрченко Э.Н.
, Солодовников С.Ф.
, Грачева Л.С.
, Клевцова Р.Ф.
Кристаллическая структура и ИК-спектры ди-μ-хлоро-бис[(диизопропилфосфит) (диизопропилфосфито)(карбонил) хлорородия(III)] ([RhCl2(CO){P(OC3H7)2O}2H]2)
Журнал структурной химии. 1982. Т.23. №3. С.79-85. РИНЦ
Кристаллическая структура и ИК-спектры ди-μ-хлоро-бис[(диизопропилфосфит) (диизопропилфосфито)(карбонил) хлорородия(III)] ([RhCl2(CO){P(OC3H7)2O}2H]2)
Журнал структурной химии. 1982. Т.23. №3. С.79-85. РИНЦ
Dates:
Submitted: | Dec 23, 1981 |
Published print: | May 1, 1982 |
Identifiers:
Web of science | WOS:A1982PW27200010 |
Scopus | 2-s2.0-34250153552 |
Elibrary | 30857678 |
OpenAlex | W1974273941 |
Citing:
Пока нет цитирований