Calculation of Force Constants of EX3 Molecules (D3h ) by Effective Potential Method Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 1990, Volume: 31, Number: 4, Pages: 551-555 Pages count : 5 DOI: 10.1007/BF00752482 | ||
Tags | Physical Chemistry; Inorganic Chemistry; Force Constant; Potential Method; Effective Potential Method | ||
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Abstract:
An expression is proposed in general form for the potential energy of tetraatomic molecules EX 3 with D~h symmetry, through which all normal vibrations can be described, the expression embodying terms determining the partial energies of chemical bonds. The expression for the potential contains those same parameters and functional relationships that had been described previously for pentaatomic tetrahedrai molecules EX4. All parameters of the potentials and the force constants of the EX~ molecule have been found, it is shown that, the same as in the case of EX4, the partial energies of the chemical bonds correlate linearly with the experimental values of the lengths of these same bonds.
Cite:
Bugaev V.I.
, Bulgakov N.N.
, Yurchenko E.N.
Calculation of Force Constants of EX3 Molecules (D3h ) by Effective Potential Method
Journal of Structural Chemistry. 1990. V.31. N4. P.551-555. DOI: 10.1007/BF00752482 WOS Scopus РИНЦ
Calculation of Force Constants of EX3 Molecules (D3h ) by Effective Potential Method
Journal of Structural Chemistry. 1990. V.31. N4. P.551-555. DOI: 10.1007/BF00752482 WOS Scopus РИНЦ
Original:
Бугаев В.И.
, Булгаков Н.Н.
, Юрченко Э.Н.
Расчет силовых постоянных молекул ЭХ3 (D3h) методом эффективных потенциалов
Журнал структурной химии. 1990. Т.31. №4. С.29-34. РИНЦ
Расчет силовых постоянных молекул ЭХ3 (D3h) методом эффективных потенциалов
Журнал структурной химии. 1990. Т.31. №4. С.29-34. РИНЦ
Dates:
Submitted: | Nov 14, 1988 |
Published print: | Jul 1, 1990 |
Identifiers:
Web of science | WOS:A1990HQ34800006 |
Scopus | 2-s2.0-34249954513 |
Elibrary | 21859925 |
OpenAlex | W2343337018 |
Citing:
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