IR Study of the Structure of Palladium(II) Acetate in Chloroform, Acetic Acid, and Their Mixtures in Solution and in Liquid-Solid Subsurface Layers Review
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 2000, Volume: 41, Number: 3, Pages: 440-445 Pages count : 6 DOI: 10.1007/BF02742003 | ||
Tags | Palladium; Subsurface Layer; Chloroform Solution; HOAc; Cyclic Dimer | ||
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Abstract:
It is found that cyclic trimer I and linear dimer II are the molecular states of palladium(II) acetate in its 1. 10-3-0.7 M chloroform solutions. The mole fraction of dimer II is higher in dilute solutions. Even with small acetic acid (HOAc) additions the I↔II equilibrium is shifted toward I because of the variation of the composition of the outer-spheric solvation shells. The content of II in the 0.1 M solution of PdAc2 in 50 vol. % HOAc+CHCl3 is 10%. However, in the thin subsurface layers of this solution at the interface CaF2 -solution, the I↔II equilibrium is slowly shifted toward II whose concentration after 60 min is 22%. This may be caused by structuring of the liquid phase in the subsurface layers during the measured time.
Cite:
Stoyanov E.S.
IR Study of the Structure of Palladium(II) Acetate in Chloroform, Acetic Acid, and Their Mixtures in Solution and in Liquid-Solid Subsurface Layers
Journal of Structural Chemistry. 2000. V.41. N3. P.440-445. DOI: 10.1007/BF02742003 WOS Scopus РИНЦ РИНЦ
IR Study of the Structure of Palladium(II) Acetate in Chloroform, Acetic Acid, and Their Mixtures in Solution and in Liquid-Solid Subsurface Layers
Journal of Structural Chemistry. 2000. V.41. N3. P.440-445. DOI: 10.1007/BF02742003 WOS Scopus РИНЦ РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Стоянов Е.С.
ИК спектроскопическое исследование строения ацетата палладия(II) в хлороформе, уксусной кислоте и в их смесях в объеме растворов и в приповерхностных слоях жидкость — твердая фаза
Журнал структурной химии. 2000. Т.41. №3. С.540-546. РИНЦ
ИК спектроскопическое исследование строения ацетата палладия(II) в хлороформе, уксусной кислоте и в их смесях в объеме растворов и в приповерхностных слоях жидкость — твердая фаза
Журнал структурной химии. 2000. Т.41. №3. С.540-546. РИНЦ
Dates:
Submitted: | May 6, 1999 |
Published print: | May 1, 2000 |
Identifiers:
Web of science | WOS:000165977600013 |
Scopus | 2-s2.0-0034559214 |
Elibrary | 26577979 , 43190470 |
Chemical Abstracts | 2001:2603 |
Chemical Abstracts (print) | 134:86376 |
OpenAlex | W2060128731 |