Cationic Complexes of Eu(III) and Sr(II) with Diphosphine Dioxides in Organic Extracts Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 2005, Volume: 46, Number: 5, Pages: 829-838 Pages count : 10 DOI: 10.1007/s10947-006-0207-x | ||||
Tags | Diphosphine dioxides, Eu(III) and Sr(II) complexes, IR spectroscopy | ||||
Authors |
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Affiliations |
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Funding (2)
1 | Civilian Research and Development Foundation | RC2-2342-ST-02 |
2 | United States Department of Energy | 81895 |
Abstract:
IR spectroscopy was used to study the structure and composition of Eu(III) and Sr(II) complexes formed by cation-exchange extraction of these metals from their aqueous nitrate solutions with dichlorethane solutions of mixtures of chlorinated cobalt(III) dicarbollide (CCD) as a superacid with diphenyldiphosphine dioxides containing a methyl (Me-DPDO), ethyl (Et-DPDO), or polyoxyethylene bridge between two phosphorus atoms of phosphine oxide groups. At molar ratios DPDO/CCD ≤ 1, [Eu(H2O)nL4]3+ complexes are formed in organic phases, whereas with an excess of DPDO relative to CCD, Eu(NO3)L 4 2+ complexes are formed, where L = Me-or Et-DPDO. Polyoxyethylenediphosphine dioxide forms anhydrous complexes of composition Eu:L = 1:1 and 1:2 with Eu(III) and outer-spheric complexes of composition Sr:L = 1:1 and 1:2 with Sr(II), where the organic ligand molecules envelop the hydrated Sr(H2O) n 2+ cation. The peculiarities of extraction of the complexes are explained based on data about their composition and structure.
Cite:
Stoyanov E.S.
, Vorobʹeva T.P.
, Smirnov I.V.
Cationic Complexes of Eu(III) and Sr(II) with Diphosphine Dioxides in Organic Extracts
Journal of Structural Chemistry. 2005. V.46. N5. P.829-838. DOI: 10.1007/s10947-006-0207-x WOS Scopus РИНЦ
Cationic Complexes of Eu(III) and Sr(II) with Diphosphine Dioxides in Organic Extracts
Journal of Structural Chemistry. 2005. V.46. N5. P.829-838. DOI: 10.1007/s10947-006-0207-x WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Стоянов Е.С.
, Воробьева Т.П.
, Смирнов И.В.
Катионные комплексы Eu(III) И Sr(II) с дифосфиндиоксидами в органических экстрактах
Журнал структурной химии. 2005. Т.46. №5. С.859-868. РИНЦ
Катионные комплексы Eu(III) И Sr(II) с дифосфиндиоксидами в органических экстрактах
Журнал структурной химии. 2005. Т.46. №5. С.859-868. РИНЦ
Dates:
Submitted: | Nov 12, 2004 |
Published print: | Sep 1, 2005 |
Identifiers:
Web of science | WOS:000240067400008 |
Scopus | 2-s2.0-33747068582 |
Elibrary | 24940345 |
Chemical Abstracts | 2006:788618 |
Chemical Abstracts (print) | 146:213876 |
OpenAlex | W2090260707 |