Hydrolysis of Volatile Ammonium Oxofluorotitanate According to 19 F, 17 O, and 49 Ti NMR Data Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 2004, Volume: 45, Number: 1, Pages: 74-82 Pages count : 7 DOI: 10.1023/B:JORY.0000041503.37439.6b | ||||
Tags | 19F, 17O, 49Ti NMR, ammonium oxofluorotitanate, hydrolysis, oligomerization | ||||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 01-03-32719 |
Abstract:
Hydrolysis of NH4TiOxF5-2x (x≤0.4) (I) was investigated by 19F, 17O, and 49Ti NMR. The interaction of complex I with water is accompanied by the formation of [TiF6]2- and multinuclear titanium forms. The composition of the main forms resulting from hydrolysis of I has been established. The bonding of titanium octahedra into dimers and other oligomers occurs by formation of hydroxyl bridges, considerably lowering the pH of the solution. Close analogy has been found between hydrolysis of the title complex and that of titanium tetrafluoride.
Cite:
Laptash N.M.
, Fedotov M.A.
, Maslennikova I.G.
Hydrolysis of Volatile Ammonium Oxofluorotitanate According to 19 F, 17 O, and 49 Ti NMR Data
Journal of Structural Chemistry. 2004. V.45. N1. P.74-82. DOI: 10.1023/B:JORY.0000041503.37439.6b WOS Scopus РИНЦ
Hydrolysis of Volatile Ammonium Oxofluorotitanate According to 19 F, 17 O, and 49 Ti NMR Data
Journal of Structural Chemistry. 2004. V.45. N1. P.74-82. DOI: 10.1023/B:JORY.0000041503.37439.6b WOS Scopus РИНЦ
Original:
Лапташ Н.М.
, Федотов М.А.
, Масленникова И.Г.
Гидролиз летучего оксофторотитаната аммония по данным ЯМР 19F, 17O, 49Ti
Журнал структурной химии. 2004. Т.45. №1. С.77-85. РИНЦ
Гидролиз летучего оксофторотитаната аммония по данным ЯМР 19F, 17O, 49Ti
Журнал структурной химии. 2004. Т.45. №1. С.77-85. РИНЦ
Dates:
Submitted: | Jan 15, 2003 |
Published print: | Jan 1, 2004 |
Identifiers:
Web of science | WOS:000224769000011 |
Scopus | 2-s2.0-4544308222 |
Elibrary | 14355929 |
Chemical Abstracts | 2004:770218 |
Chemical Abstracts (print) | 142:231866 |
OpenAlex | W2034145039 |