Role of the Cu–Co Alloy and Cobalt Carbide in Higher Alcohol Synthesis Full article
Conference |
Physical Methods for Catalytic Research at the Molecular Level: International memorial K.I. Zamaraev conference 28 Jun - 2 Jul 1999 , Novosibirsk |
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Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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Output data | Year: 2000, Volume: 158, Number: 1, Pages: 389-393 Pages count : 5 DOI: 10.1016/S1381-1169(00)00110-2 | ||
Tags | Cobalt carbide, Cu-Co alloy, Cu-Co based catalyst, Higher alcohol synthesis, In situ XRD | ||
Authors |
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Affiliations |
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Abstract:
Formation and decomposition of the Cu–Co alloy and Co2C were studied using in situ X-ray diffraction (XRD), TG-DTA and TEM techniques. Cu–Co alloy with ratio Cu/Co=1:1 has been obtained under treatment of CuCoO2 with hydrogen at 230–300°C. Co2C was formed from Cu–Co alloy at 280–310°C and decomposed at 390–400°C under CO. It was shown that the role of Cu–Co alloy consisted in formation of cobalt carbide was able to activate CO undissociatively that led to oxygenates synthesis.
Cite:
Volkova G.G.
, Yurieva T.M.
, Plyasova L.M.
, Naumova M.I.
, Zaikovskii V.I.
Role of the Cu–Co Alloy and Cobalt Carbide in Higher Alcohol Synthesis
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.389-393. DOI: 10.1016/S1381-1169(00)00110-2 WOS Scopus РИНЦ
Role of the Cu–Co Alloy and Cobalt Carbide in Higher Alcohol Synthesis
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.389-393. DOI: 10.1016/S1381-1169(00)00110-2 WOS Scopus РИНЦ
Dates:
Published online: | Jul 18, 2000 |
Published print: | Sep 8, 2000 |
Identifiers:
Web of science | WOS:000089201200053 |
Scopus | 2-s2.0-0034622696 |
Elibrary | 13347807 |
Chemical Abstracts | 2000:498714 |
Chemical Abstracts (print) | 133:336801 |
OpenAlex | W2026036367 |