Titanium- and Zirconium-Monosubstituted Polyoxometalates as Molecular Models for Studying Mechanisms of Oxidation Catalysis Review
Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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Output data | Year: 2007, Volume: 262, Number: 1-2, Pages: 7-24 Pages count : 18 DOI: 10.1016/j.molcata.2006.08.023 | ||
Tags | Hydrogen peroxide, Mechanism, Oxidation, Peroxo species, Polyoxometalates, Single-site catalysts, Titanium, Zirconium | ||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 04-03-32113 |
2 | Russian Foundation for Basic Research | 01-03-32852 |
Abstract:
Recent developments in the application of titanium- and zirconium-monosubstituted Keggin-type polyoxometalates (Ti- and Zr-POMs) as molecular models for studying mechanisms of H2O2-based selective oxidation catalysis are reviewed. The similarity in the catalytic behavior of Ti- and Zr-POMs and heterogeneous Ti(IV) and Zr(IV) single-site selective oxidation catalysts is demonstrated. The progress on the synthesis of Ti- and Zr-POMs, studying their interaction with H2O and H2O2, and characterization of the peroxo species formed are surveyed, with special emphasis being placed on the role of protons in the activation of the peroxo species.
Cite:
Kholdeeva O.A.
, Maksimovskaya R.I.
Titanium- and Zirconium-Monosubstituted Polyoxometalates as Molecular Models for Studying Mechanisms of Oxidation Catalysis
Journal of Molecular Catalysis A: Chemical. 2007. V.262. N1-2. P.7-24. DOI: 10.1016/j.molcata.2006.08.023 WOS Scopus РИНЦ
Titanium- and Zirconium-Monosubstituted Polyoxometalates as Molecular Models for Studying Mechanisms of Oxidation Catalysis
Journal of Molecular Catalysis A: Chemical. 2007. V.262. N1-2. P.7-24. DOI: 10.1016/j.molcata.2006.08.023 WOS Scopus РИНЦ
Dates:
Published online: | Aug 18, 2006 |
Published print: | Feb 1, 2007 |
Identifiers:
Web of science | WOS:000244183400003 |
Scopus | 2-s2.0-33846181390 |
Elibrary | 13536923 |
Chemical Abstracts | 2007:79653 |
Chemical Abstracts (print) | 146:295343 |
OpenAlex | W2023327551 |