Kinetic Peculiarities of α-Pinene Oxidation by Molecular Oxygen
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Applied Catalysis A: General
ISSN: 0926-860X
, E-ISSN: 1873-3875
|
| Output data |
Year: 2004,
Volume: 272,
Number: 1-2,
Pages: 109-114
Pages count
: 6
DOI:
10.1016/j.apcata.2004.05.020
|
| Tags |
α-Pinene oxidation, Kinetics, Mechanism, Verbenol synthesis, Verbenyl-hydroperoxide hydrogenation on Pd/C |
| Authors |
Ancel J.E.
1
,
Maksimchuk N.V.
1
,
Simakova I.L.
1
,
Semikolenov V.A.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia
|
|
Funding (1)
|
1
|
Civilian Research and Development Foundation
|
NO-008-X1
|
Kinetic peculiarities of α-pinene liquid-phase oxidation by molecular oxygen were studied (in a temperature range of 343–393 K and at oxygen pressure within 0.5–6 bar range). The process proceeds selectively at a low α-pinene conversion and the main products are verbenyl-hydroperoxide and α-pinene epoxide. The products ratio depends slightly on temperature, oxygen pressure and α-pinene conversion. The kinetic equation for the reaction rate was suggested.