Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst Full article
Journal |
Scripta Materialia
ISSN: 1359-6462 |
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Output data | Year: 2001, Volume: 44, Number: 8-9, Pages: 1663-1666 Pages count : 4 DOI: 10.1016/S1359-6462(01)00877-6 | ||||
Tags | Aero-gel, Catalysis, Electron spin resonance, Nanocrystal, Surface, TEM | ||||
Authors |
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Abstract:
Nanocyrstals of MgO having 4 nm average crystallite sizes with 450–550 m2/g surface area were prepared by the Aero-gel preparation method (AP-MgO). Dehydrohalogenation of 1-chlorobutane was performed using AP-MgO as a catalyst; And 1-butene is the selective product formed even after several cycles of 1-chlorobutane injections. AP-MgO was allowed to react with Cl2, which resulted in the formation of a highly reactive adduct which has a capability to selectively chlorinate propane.
Cite:
Richards R.
, Mulukutla R.S.
, Mishakov I.
, Chesnokov V.
, Volodin A.
, Zaikovski V.
, Sun N.
, Klabunde K.J.
Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst
Scripta Materialia. 2001. V.44. N8-9. P.1663-1666. DOI: 10.1016/S1359-6462(01)00877-6 WOS Scopus РИНЦ
Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst
Scripta Materialia. 2001. V.44. N8-9. P.1663-1666. DOI: 10.1016/S1359-6462(01)00877-6 WOS Scopus РИНЦ
Dates:
Submitted: | Aug 21, 2000 |
Accepted: | Nov 22, 2000 |
Published print: | May 18, 2001 |
Published online: | Jun 13, 2001 |
Identifiers:
Web of science | WOS:000169389400099 |
Scopus | 2-s2.0-0035906768 |
Elibrary | 13385558 |
Chemical Abstracts | 2001:440766 |
Chemical Abstracts (print) | 135:127683 |
OpenAlex | W1983987673 |