Effect of Supercritical Water Density on the Rate Constant of Aliphatic Nitrocompounds Decomposition Full article
Journal |
The Journal of Supercritical Fluids
ISSN: 0896-8446 , E-ISSN: 1872-8162 |
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Output data | Year: 2005, Volume: 33, Number: 3, Pages: 243-246 Pages count : 4 DOI: 10.1016/j.supflu.2004.08.001 | ||||
Tags | Chemical reaction, Decomposition, Pressure effect, Supercritical water | ||||
Authors |
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Affiliations |
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Funding (1)
1 | International Science and Technology Center | 2383 |
Abstract:
It was shown experimentally that the rate of aliphatic nitrocompounds decomposition in supercritical water (SCW) depends on pressure/density at constant temperature. The SCW density dependence of the apparent rate constant of decomposition for each of three compounds under consideration (nitromethane, nitroethane and 1-nitropropane) was found to correlate with the density dependence of the H3O+ concentration in dissociated SCW. The rate constant of RNO2 decomposition in SCW decreased with increasing the length of hydrocarbon radical R.
Cite:
Anikeev V.I.
, Yermakova A.
, Semikolenov V.A.
, Goto M.
Effect of Supercritical Water Density on the Rate Constant of Aliphatic Nitrocompounds Decomposition
The Journal of Supercritical Fluids. 2005. V.33. N3. P.243-246. DOI: 10.1016/j.supflu.2004.08.001 WOS Scopus РИНЦ
Effect of Supercritical Water Density on the Rate Constant of Aliphatic Nitrocompounds Decomposition
The Journal of Supercritical Fluids. 2005. V.33. N3. P.243-246. DOI: 10.1016/j.supflu.2004.08.001 WOS Scopus РИНЦ
Dates:
Submitted: | Jul 28, 2004 |
Accepted: | Aug 2, 2004 |
Published online: | Oct 2, 2004 |
Published print: | Mar 1, 2005 |
Identifiers:
Web of science | WOS:000227412400005 |
Scopus | 2-s2.0-11144326754 |
Elibrary | 13473676 |
Chemical Abstracts | 2004:1125115 |
Chemical Abstracts (print) | 142:340963 |
OpenAlex | W1986080001 |