NMR and EPR Spectroscopy Applied to Homogeneous Catalysis
Full article
Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
Journal |
Kinetics and Catalysis
ISSN: 0023-1584
, E-ISSN: 1608-3210
|
Output data |
Year: 2015,
Volume: 56,
Number: 4,
Pages: 484-492
Pages count
: 9
DOI:
10.1134/S0023158415040175
|
Tags |
active sites of catalysts, EPR spectroscopy, homogeneous catalysis, NMR spectroscopy, olefin epoxidation, olefin polymerization |
Authors |
Talzi E.P.
1,2
,
Brylyakov K.P.
1,2
,
Lyakin O.Yu.
1,2
,
Zima A.M.
1,2
,
Soshnikov I.E.
1,2
|
Affiliations |
1 |
Novosibirsk State University, Novosibirsk, 630090 Russia
|
2 |
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
|
|
Funding (1)
1
|
Russian Science Foundation
|
14-13-00158
|
The article deals with applying NMR and EPR spectroscopy to the study of the active sites of catalysts in two important classes of reactions: enantioselective olefin epoxidation with hydrogen peroxide catalyzed by iron aminopyridine complexes and olefin polymerization in the presence of titanium and vanadium post-metallocene catalysts.