Role of the Surface Hydroxyl Groups of Modified Titanium Oxide in Catalytic Ethylene Oxide Hydration Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2011, Volume: 52, Number: 5, Pages: 659-671 Pages count : 13 DOI: 10.1134/S0023158411050193 | ||||||||
Tags | Proton Transfer; Ethylene Oxide; Reaction Path; Phosphorus Atom; Titanium Atom | ||||||||
Authors |
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Affiliations |
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Funding (2)
1 | Council for Grants of the President of the Russian Federation | НШ-65264.2010.3 |
2 | Russian Foundation for Basic Research | 09-03-00133 |
Abstract:
A quantum-chemical study of the mechanism of ethylene oxide hydration on titanium oxide (anatase) modified with phosphorus additives was performed. It was demonstrated that the hydroxyl groups of the anatase surface are of importance for the activation interaction of ethylene oxide with the catalyst surface. The activation of the ethylene oxide molecule and proton transfer occur with the participation of these hydroxyl groups. It was found that the modification of the titanium oxide surface with phosphorus additives plays a crucial role in proton transfer.
Cite:
Zavelev D.E.
, Tsodikov M.V.
, Zhidomirov G.M.
, Kozlovskii R.A.
Role of the Surface Hydroxyl Groups of Modified Titanium Oxide in Catalytic Ethylene Oxide Hydration
Kinetics and Catalysis. 2011. V.52. N5. P.659-671. DOI: 10.1134/S0023158411050193 WOS Scopus РИНЦ
Role of the Surface Hydroxyl Groups of Modified Titanium Oxide in Catalytic Ethylene Oxide Hydration
Kinetics and Catalysis. 2011. V.52. N5. P.659-671. DOI: 10.1134/S0023158411050193 WOS Scopus РИНЦ
Original:
Завелев Д.Е.
, Цодиков М.В.
, Жидомиров Г.М.
, Козловский Р.А.
О роли поверхностных гидроксильных групп модифицированного оксида титана в каталитическом процессе гидратации этиленоксида
Кинетика и катализ. 2011. Т.52. №5. С.675-687. РИНЦ
О роли поверхностных гидроксильных групп модифицированного оксида титана в каталитическом процессе гидратации этиленоксида
Кинетика и катализ. 2011. Т.52. №5. С.675-687. РИНЦ
Dates:
Submitted: | Oct 12, 2010 |
Published print: | Sep 1, 2011 |
Published online: | Sep 29, 2011 |
Identifiers:
Web of science | WOS:000295331300004 |
Scopus | 2-s2.0-80053602112 |
Elibrary | 18008432 |
Chemical Abstracts | 2011:1225758 |
Chemical Abstracts (print) | 157:44591 |
OpenAlex | W1985079362 |