Low Temperature Hydrogen Purification from CO for Fuel Cell Application over Copper–Ceria Catalysts Supported on Different Oxides Full article
Journal |
International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487 |
||||
---|---|---|---|---|---|
Output data | Year: 2011, Volume: 36, Number: 1, Pages: 1271-1275 Pages count : 5 DOI: 10.1016/j.ijhydene.2010.06.126 | ||||
Tags | Ceria, Copper, PROX, XPS, XRD, Zirconia | ||||
Authors |
|
||||
Affiliations |
|
Funding (1)
1 | Russian Foundation for Basic Research | 09-03-90424 |
Abstract:
The CuO–CeO2–MeOx (Me = Zr, Ti, Mn, Al; x = 1.5–2) solids were tested in the preferential CO oxidation reaction in hydrogen-rich gas mixtures (PROX). We study an effect of a support (MeOx) the CO conversion and selectivity in the PROX reaction showing that monoclinic zirconia (m-zirconia) with low surface area is the most effective support. The optimal catalyst composition was determined by varying copper and ceria loadings over m-zirconia. XRD and XPS studies indicate that a good catalytic performance of m-zirconia supported copper–ceria catalysts may be attributed to the presence of dispersed Cu-containing species that interact with CeO2 and ZrO2.
Cite:
Kosmambetova G.R.
, Moroz E.M.
, Guralsky A.V.
, Pakharukova V.P.
, Boronin A.I.
, Ivashchenko T.S.
, Gritsenko V.I.
, Strizhak P.E.
Low Temperature Hydrogen Purification from CO for Fuel Cell Application over Copper–Ceria Catalysts Supported on Different Oxides
International Journal of Hydrogen Energy. 2011. V.36. N1. P.1271-1275. DOI: 10.1016/j.ijhydene.2010.06.126 WOS Scopus РИНЦ
Low Temperature Hydrogen Purification from CO for Fuel Cell Application over Copper–Ceria Catalysts Supported on Different Oxides
International Journal of Hydrogen Energy. 2011. V.36. N1. P.1271-1275. DOI: 10.1016/j.ijhydene.2010.06.126 WOS Scopus РИНЦ
Dates:
Submitted: | Jun 25, 2010 |
Accepted: | Jun 25, 2010 |
Published online: | Aug 19, 2010 |
Published print: | Jan 1, 2011 |
Identifiers:
Web of science | WOS:000288102700147 |
Scopus | 2-s2.0-79251627442 |
Elibrary | 23957315 |
Chemical Abstracts | 2011:124969 |
Chemical Abstracts (print) | 154:314328 |
OpenAlex | W2016222053 |