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Solid-Phase Condensation of Rhodium(III) Aqua Sulfates Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613
Output data Year: 2011, Volume: 56, Number: 10, Pages: 1609-1616 Pages count : 8 DOI: 10.1134/S0036023611100263
Authors Vorobʹyova S.N. 1 , Belyaev A.V. 1 , Fedotov M.A. 2 , Yushina I.V. 1 , Nedoseikina T.I. 1
Affiliations
1 Nikolaev Institute of Inorganic Chemistry SB RAS
2 Boreskov Institute of Catalysis SB RAS

Abstract: Solid-phase condensation of rhodium(III) aqua sulfates yielding oligomeric rhodium(III) aqua sulfate complexes was revealed. The isothermal dehydration of rhodium(III) aqua sulfates under thermal diffusion conditions in the temperature range 100–130°C was studied, and effective rate constants and activation energies were determined. The solid phases of dehydration products were studied by X-ray powder diffraction and IR spectroscopy, and solutions of polymeric phases were studied by 103Rh and 17O NMR, electronic absorption spectroscopy, chromatography, and electrophoresis.
Cite: Vorobʹyova S.N. , Belyaev A.V. , Fedotov M.A. , Yushina I.V. , Nedoseikina T.I.
Solid-Phase Condensation of Rhodium(III) Aqua Sulfates
Russian Journal of Inorganic Chemistry. 2011. V.56. N10. P.1609-1616. DOI: 10.1134/S0036023611100263 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Воробьёва С.Н. , Беляев А.В. , Федотов М.А. , Юшина И.В. , Недосейкина Т.И.
Твердофазная конденсация сульфатов акваиона родия(III)
Журнал неорганической химии. 2011. Т.56. №10. С.1689-1696. publication_identifier_short.rinz_identifier_type
Dates:
Submitted: May 12, 2010
Published print: Oct 1, 2011
Published online: Oct 11, 2011
Identifiers:
publication_identifier.wos_identifier_type WOS:000295784600017
publication_identifier.scopus_identifier_type 2-s2.0-80053977387
publication_identifier.rinz_identifier_type 18009132
publication_identifier.accession_number_identifier_type 2011:1287093
publication_identifier.chemical_accession_number_identifier_type 157:307187
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