One-Pot Process of Anthraquinone Synthesis in the Presence of Mo-V-P Heteropoly Acid Solutions as a Bifunctional Catalysts
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Modern Research in Catalysis
ISSN: 2168-4480
, E-ISSN: 2168-4499
|
| Output data |
Year: 2013,
Number: 2,
Pages: 90-92
Pages count
: 3
DOI:
10.4236/mrc.2013.23013
|
| Authors |
Gogin Leonid
1
,
Zhizhina Elena
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis, Novosibirsk, Russia
|
|
Acid-catalytic 1,3-butadiene condensation with para-quinones followed by the obtained product oxidation may be per- formed in one stage as one-pot process, if assisted by the aqueous solutions of Mo-V-P heteropoly acids with a compo- sition of HaPzMoyVxOb. 1,4-naphthoquinone condensation with 1,3-butadiene in the HPA solutions with no organic solvents yields 9,10-anthraquinone (AQ) mixed with tetrahydro-AQ (THA) and dihydro-AQ (DHA). However, AQ yield and its purity may be considerably improved by using water-mixable organic solvents, e.g., acetone, 1,4-dioxane, as well as high vanadium content HPA such as H15P4Mo18V7O89 and H17P3Mo16V10O89. Process optimization provides 70% yield of reaction product containing no less than 90% AQ.