Mechanism and Principles of Organization of Catalytic Radical Heterogeneous–Homogeneous Processes Review
Journal |
Review Journal of Chemistry
ISSN: 2079-9780 , E-ISSN: 2079-9799 |
||
---|---|---|---|
Output data | Year: 2011, Volume: 1, Number: 4, Pages: 344-358 Pages count : 15 DOI: 10.1134/S2079978011030034 | ||
Tags | catalysis, pyrolysis, hydrocarbons, dichloroethane, chain mechanism, radical-chain process | ||
Authors |
|
||
Affiliations |
|
Abstract:
The mechanisms and regularities of unbranched radicalchain reactions are considered
using the example of the pyrolysis of hydrocarbons or dichloroethane involving heterogeneous catalysts. The phenomenological model of such reactions and experimental proof of its validity are presented. An effect of “ignition” of the catalyst activity is discovered, and its nature is explained. The concept of “catalysis sphere” is introduced, and the conditions of its existence and functioning are determined. The experimental criteria for the occurrence of the sphere are found. The offered mechanism creates the possibility for a purposeful selection and synthesis of catalysts and for a choice of means of the technological organization of the heterogeneous–homogeneous processes with the participation of radicals.
Cite:
Vasilʹeva N.A.
, Buyanov R.A.
Mechanism and Principles of Organization of Catalytic Radical Heterogeneous–Homogeneous Processes
Review Journal of Chemistry. 2011. V.1. N4. P.344-358. DOI: 10.1134/S2079978011030034 РИНЦ
Mechanism and Principles of Organization of Catalytic Radical Heterogeneous–Homogeneous Processes
Review Journal of Chemistry. 2011. V.1. N4. P.344-358. DOI: 10.1134/S2079978011030034 РИНЦ
Original:
Васильева Н.А.
, Буянов Р.А.
Механизм и принципы организации каталитических радикальных гетерогенно-гомогенных процессов
Обзорный журнал по химии. 2011. Т.1. №4. С.334-349. РИНЦ
Механизм и принципы организации каталитических радикальных гетерогенно-гомогенных процессов
Обзорный журнал по химии. 2011. Т.1. №4. С.334-349. РИНЦ
Dates:
Submitted: | Sep 17, 2010 |
Accepted: | Apr 4, 2011 |
Published print: | Oct 1, 2011 |
Published online: | Nov 26, 2011 |
Identifiers:
Elibrary | 40937016 |
OpenAlex | W2088166805 |
Citing:
DB | Citing |
---|---|
OpenAlex | 1 |