Rate-Determining Stage in NO SCR with Propane on Low-Exchanged Cu-ZSM-5 Catalyst Full article
Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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Output data | Year: 2000, Volume: 64, Number: 2-4, Pages: 129-134 Pages count : 6 DOI: 10.1023/A:1019007624834 | ||||
Tags | adsorbed acetone oxime, Cu-ZSM-5, FTIR spectra, isomerization of 2-nitrosopropane, kinetics of reaction with NO, Kinetics of the separate steps of the reaction, NO reduction, pulse method, TPD | ||||
Authors |
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Affiliations |
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Funding (1)
1 | International Science Foundation | a98-378 |
Abstract:
The kinetics of the NO SCR with propane has been studied on a low‐exchanged Cu‐ZSM‐5 catalyst. The study of the kinetics of individual reaction stages (2‐nitrosopropane isomerization to acetone oxime and reaction of adsorbed acetone oxime with gaseous NO) has shown that the NO reaction with acetone oxime is the rate‐determining stage in the whole chain of transformations leading to the formation of molecular nitrogen in the low‐temperature region below 300 °C. The kinetic analysis of the reaction has revealed that at the temperatures above 300 °C propane plays a more important role.
Cite:
Rebrov E.V.
, Simakov A.V.
, Sazonova N.N.
, Stoyanov E.S.
Rate-Determining Stage in NO SCR with Propane on Low-Exchanged Cu-ZSM-5 Catalyst
Catalysis Letters. 2000. V.64. N2-4. P.129-134. DOI: 10.1023/A:1019007624834 WOS Scopus РИНЦ
Rate-Determining Stage in NO SCR with Propane on Low-Exchanged Cu-ZSM-5 Catalyst
Catalysis Letters. 2000. V.64. N2-4. P.129-134. DOI: 10.1023/A:1019007624834 WOS Scopus РИНЦ
Dates:
Submitted: | Jun 20, 1999 |
Accepted: | Nov 29, 1999 |
Published print: | Feb 1, 2000 |
Identifiers:
Web of science | WOS:000085099300010 |
Scopus | 2-s2.0-0034144241 |
Elibrary | 13343638 |
Chemical Abstracts | 2000:170372 |
Chemical Abstracts (print) | 132:184720 |
OpenAlex | W2148140070 |