Synthesis and Characterization of a Novel Tantalum Chalcogen-Rich Molecular Cluster with Square Planar Metal Core Full article
Journal |
Inorganic Chemistry
ISSN: 0020-1669 , E-ISSN: 1520-510X |
||||
---|---|---|---|---|---|
Output data | Year: 2004, Volume: 43, Number: 25, Pages: 7966-7968 Pages count : 3 DOI: 10.1021/ic0489239 | ||||
Tags | chalcogen; indium; ligand; metal; selenium; tantalum | ||||
Authors |
|
||||
Affiliations |
|
Funding (4)
1 | Russian Foundation for Basic Research | 02-07-90322 |
2 | Russian Foundation for Basic Research | 02-03-32604 |
3 | Russian Foundation for Basic Research | 02-03-32319 |
4 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 2356 |
Abstract:
Black single crystals of Ta4Se9I8 are obtained in a high yield by heating Ta, Se, and I2 at 300 °C in 1:2.2:1.0 molar ratio. In the structure, the tantalum atoms form a square, with four Se2 ligands bridging the Ta−Ta edges and one capping the square. Each Ta atom has two terminal iodine atoms. The compound is diamagnetic and has only two electrons for metal−metal bonding.
Cite:
Sokolov M.N.
, Gushchin A.L.
, Virovets A.V.
, Peresypkina E.V.
, Kozlova S.G.
, Fedin V.P.
Synthesis and Characterization of a Novel Tantalum Chalcogen-Rich Molecular Cluster with Square Planar Metal Core
Inorganic Chemistry. 2004. V.43. N25. P.7966-7968. DOI: 10.1021/ic0489239 WOS Scopus РИНЦ
Synthesis and Characterization of a Novel Tantalum Chalcogen-Rich Molecular Cluster with Square Planar Metal Core
Inorganic Chemistry. 2004. V.43. N25. P.7966-7968. DOI: 10.1021/ic0489239 WOS Scopus РИНЦ
Dates:
Submitted: | Aug 5, 2004 |
Published online: | Nov 10, 2004 |
Published print: | Dec 1, 2004 |
Identifiers:
Web of science | WOS:000225717700013 |
Scopus | 2-s2.0-10044225630 |
Elibrary | 14603300 |
Chemical Abstracts | 2004:949425 |
Chemical Abstracts (print) | 142:105938 |
OpenAlex | W2146945208 |