Synthesis, Characterization, and Reactivity of Ti(IV)-Monosubstituted Keggin Polyoxometalates Full article
Journal |
Inorganic Chemistry
ISSN: 0020-1669 , E-ISSN: 1520-510X |
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Output data | Year: 2005, Volume: 44, Number: 5, Pages: 1635-1642 Pages count : 8 DOI: 10.1021/ic0490829 | ||
Tags | METHYL PHENYL SULFIDE; HYDROGEN-PEROXIDE; W-183 NMR; OXIDATION; TITANIUM; COMPLEXES; HETEROPOLYTUNGSTATES; CHEMISTRY; CATALYSTS; 2,3,6-TRIMETHYLPHENOL | ||
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Abstract:
Ti(IV)-monosubstituted Keggin polyoxometalates [Bu4N]8[(PTiW11O39)2O], [Bu4N]4[PTi(OH)W11O39], [Bu4N]4[PTi(OMe)W11O39], and [Bu4N]4[PTi(OAr)W11O39] (ArOH = 2,3,6-trimethylphenol) have been synthesized and characterized by elemental analysis, IR, UV−vis, and multinuclear (31P, 1H, 183W) NMR. Their interaction with H2O and H2O2 in MeCN has been studied, and the corresponding equilibrium constants have been estimated.
Cite:
Kholdeeva O.A.
, Trubitsina T.A.
, Maksimov G.M.
, Golovin A.V.
, Maksimovskaya R.I.
Synthesis, Characterization, and Reactivity of Ti(IV)-Monosubstituted Keggin Polyoxometalates
Inorganic Chemistry. 2005. V.44. N5. P.1635-1642. DOI: 10.1021/ic0490829 WOS Scopus РИНЦ
Synthesis, Characterization, and Reactivity of Ti(IV)-Monosubstituted Keggin Polyoxometalates
Inorganic Chemistry. 2005. V.44. N5. P.1635-1642. DOI: 10.1021/ic0490829 WOS Scopus РИНЦ
Dates:
Submitted: | Jul 12, 2004 |
Published online: | Feb 10, 2005 |
Published print: | Mar 1, 2005 |
Identifiers:
Web of science | WOS:000227346300066 |
Scopus | 2-s2.0-14744283615 |
Elibrary | 13483939 |
Chemical Abstracts | 2005:113314 |
Chemical Abstracts (print) | 142:384470 |
PMID | 15733007 |
OpenAlex | W2061387469 |