Synthesis, Characterization, and Reactivity of Ti(IV)-Monosubstituted Keggin Polyoxometalates
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Inorganic Chemistry
ISSN: 0020-1669
, E-ISSN: 1520-510X
|
| Output data |
Year: 2005,
Volume: 44,
Number: 5,
Pages: 1635-1642
Pages count
: 8
DOI:
10.1021/ic0490829
|
| Authors |
Kholdeeva Oxana A.
1
,
Trubitsina Tatiana A.
1
,
Maksimov Gennadii M.
1
,
Golovin Anatolii V.
1
,
Maksimovskaya Raisa I.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis, Lavrentieva 5, Novosibirsk 630090, Russia
|
|
Ti(IV)-monosubstituted Keggin polyoxometalates [Bu4N]8[(PTiW11O39)2O], [Bu4N]4[PTi(OH)W11O39], [Bu4N]4[PTi(OMe)W11O39], and [Bu4N]4[PTi(OAr)W11O39] (ArOH = 2,3,6-trimethylphenol) have been synthesized and characterized by elemental analysis, IR, UV−vis, and multinuclear (31P, 1H, 183W) NMR. Their interaction with H2O and H2O2 in MeCN has been studied, and the corresponding equilibrium constants have been estimated.