Properties of Cesium Hydrogen Sulfate Dispersed in Small Pores of an Inert Carrier Full article
Journal |
Inorganic Materials
ISSN: 0020-1685 , E-ISSN: 1608-3172 |
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Output data | Year: 1998, Volume: 34, Number: 12, Pages: 1266-1269 Pages count : 4 | ||||
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Abstract:
Structural and thermal transformations in (1 - x)CsHSO4/xSiO(2) (x = 0-0.8) composite protonic electrolytes containing fine-particle silicas with various pore structures (R-pore = 14-170 Angstrom) were studied by differential scanning calorimetry and x-ray diffraction. The properties of the composites were found to depend on the pore size of silica. At
R-pore = 35-70 A, the enthalpies of the phase transition and melting of CsHSO4 decrease and partial or total amorphization of CsHSO4 occurs, depending on composition. At R-pore = 170 Angstrom, a decrease in the particle size of CsHSO4 is likely to occur. The observed changes in the thermodynamic and structural properties of CsHSO4 correlate with the electrical conductivity of the composites.
Cite:
Ponomareva V.G.
, Lavrova G.V.
, Simonova L.G.
Properties of Cesium Hydrogen Sulfate Dispersed in Small Pores of an Inert Carrier
Inorganic Materials. 1998. V.34. N12. P.1266-1269. WOS Scopus РИНЦ
Properties of Cesium Hydrogen Sulfate Dispersed in Small Pores of an Inert Carrier
Inorganic Materials. 1998. V.34. N12. P.1266-1269. WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Пономарева В.Г.
, Лаврова Г.В.
, Симонова Л.Г.
Особенности поведения гидросульфата цезия в мелких порах инертного носителя
Неорганические материалы. 1998. Т.34. №12. С.1499-1502. РИНЦ
Особенности поведения гидросульфата цезия в мелких порах инертного носителя
Неорганические материалы. 1998. Т.34. №12. С.1499-1502. РИНЦ
Dates:
Submitted: | Dec 27, 1996 |
Published print: | Dec 1, 1998 |
Identifiers:
Web of science | WOS:000077352300020 |
Scopus | 2-s2.0-2542436269 |
Elibrary | 13284443 |
Chemical Abstracts | 1998:794193 |
Chemical Abstracts (print) | 130:130363 |