Mechanisms for Hydrogenation of Acetone to Isopropanol and of Carbon Oxides to Methanol over Copper-Containing Oxide Catalysts Review
Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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Output data | Year: 1996, Volume: 113, Number: 3, Pages: 455-468 Pages count : 14 DOI: 10.1016/S1381-1169(96)00272-5 | ||
Tags | Copper-containing oxide catalysts, Hydrogenation of acetone to isopropanol, Methanol synthesis from carbon oxides | ||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 95-03-08260 |
2 | Russian Foundation for Basic Research | 96-03-33887 |
Abstract:
Mechanisms for the synthesis of methanol from CO and CO2 and for the hydrogenation of acetone to isopropanol are discussed based on the recent experimental results obtained by the authors. The state of copper-containing compounds in a hydrogen medium at 200–400°C and the nature of their interaction with the reaction components were studied. Hydrogenation of carbon oxides and acetone was proposed to be the result of the ability of copper ions to reversible transformations to generate copper metal and protons. Activation of acetone and CO2 can be achieved through their interaction with Cu0, and activation of CO through its interaction with oxygen-containing sites of Cu+1OCu+1 type which are formed after oxidation of a portion of Cu0 with carbon dioxide.
Cite:
Yurieva T.M.
, Plyasova L.M.
, Makarova O.V.
, Krieger T.A.
Mechanisms for Hydrogenation of Acetone to Isopropanol and of Carbon Oxides to Methanol over Copper-Containing Oxide Catalysts
Journal of Molecular Catalysis A: Chemical. 1996. V.113. N3. P.455-468. DOI: 10.1016/S1381-1169(96)00272-5 WOS Scopus РИНЦ
Mechanisms for Hydrogenation of Acetone to Isopropanol and of Carbon Oxides to Methanol over Copper-Containing Oxide Catalysts
Journal of Molecular Catalysis A: Chemical. 1996. V.113. N3. P.455-468. DOI: 10.1016/S1381-1169(96)00272-5 WOS Scopus РИНЦ
Dates:
Submitted: | Apr 15, 1996 |
Accepted: | Jun 6, 1996 |
Published print: | Dec 10, 1996 |
Published online: | Oct 7, 1998 |
Identifiers:
Web of science | WOS:A1996VX02800004 |
Scopus | 2-s2.0-0030579532 |
Elibrary | 13244231 |
Chemical Abstracts | 1996:693224 |
Chemical Abstracts (print) | 126:74407 |
OpenAlex | W2111066056 |