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The Structure of New Heterometallic Ru/M (M = Cu, Ni, Co, Zn) Complexes Investigated by Combined Spectroscopic and Modeling Studies Full article

Common Language: Английский, Genre: Full article,
Status: Published, Source type: Original
Journal Journal of Molecular Structure
ISSN: 0022-2860
Output data Year: 2002, Volume: 611, Number: 1-3, Pages: 131-138 Pages count : 8 DOI: 10.1016/S0022-2860(02)00059-5
Tags Calixarenes, Heterometallic complexes, Quantum mechanics calculations, Ruthenium extraction, Spectroscopy
Authors Torgov V. 1 , Erenburg S. 1 , Bausk N. 1 , Stoyanov E. 2 , Kalchenko V. 3 , Varnek A. 4 , Wipff G. 4
Affiliations
1 Institute of Inorganic Chemistry, Siberian Branch Ac. Sci. Russ., Novosibirsk, Russian Federation
2 Institute of Catalysis, Siberian Branch Ac. Sci. Russ., Novosibirsk, Russian Federation
3 Institute of Organic Chemistry, National Ac. Sci., Kiev, Ukraine
4 Laboratoire MSM, UMR 7551 CNRS, Universite Louis Pasteur, 4, rue B. Pascal, 67 000 Strasbourg, France

Funding (1)

1 European Commission INCO-COPERNICUS ERB IC15-CT98-0208

Abstract: This article concerns new heterometallic Ru/M (M=Cu, Ni, Co, Zn) complexes formed upon solvent extraction of [RuNO(NO2)4OH]2− by trioctyl-phosphine oxide or calix[4]arene-tetraphosphine oxide. They have been characterised by IR, UV, EXAFS, and mass spectroscopies in hexane and dichloroethane solutions and by quantum mechanics calculations (PM3-tm, DFT B3LYP) in the gas phase. In these complexes, Ru and M are connected by OH and NO2 bridging groups.
Cite: Torgov V. , Erenburg S. , Bausk N. , Stoyanov E. , Kalchenko V. , Varnek A. , Wipff G.
The Structure of New Heterometallic Ru/M (M = Cu, Ni, Co, Zn) Complexes Investigated by Combined Spectroscopic and Modeling Studies
Journal of Molecular Structure. 2002. V.611. N1-3. P.131-138. DOI: 10.1016/S0022-2860(02)00059-5 WOS Scopus РИНЦ
Dates:
Submitted: Dec 3, 2001
Accepted: Feb 4, 2002
Published online: Mar 6, 2002
Published print: Jun 19, 2002
Identifiers:
Web of science WOS:000176144400014
Scopus 2-s2.0-0037134742
Elibrary 13405699
AN 2002:336614
CAN 137:225695
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