The Structure of New Heterometallic Ru/M (M = Cu, Ni, Co, Zn) Complexes Investigated by Combined Spectroscopic and Modeling Studies Full article
Journal |
Journal of Molecular Structure
ISSN: 0022-2860 |
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Output data | Year: 2002, Volume: 611, Number: 1-3, Pages: 131-138 Pages count : 8 DOI: 10.1016/S0022-2860(02)00059-5 | ||||||||
Tags | Calixarenes, Heterometallic complexes, Quantum mechanics calculations, Ruthenium extraction, Spectroscopy | ||||||||
Authors |
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Affiliations |
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Funding (1)
1 | European Commission | INCO-COPERNICUS ERB IC15-CT98-0208 |
Abstract:
This article concerns new heterometallic Ru/M (M=Cu, Ni, Co, Zn) complexes formed upon solvent extraction of [RuNO(NO2)4OH]2− by trioctyl-phosphine oxide or calix[4]arene-tetraphosphine oxide. They have been characterised by IR, UV, EXAFS, and mass spectroscopies in hexane and dichloroethane solutions and by quantum mechanics calculations (PM3-tm, DFT B3LYP) in the gas phase. In these complexes, Ru and M are connected by OH and NO2 bridging groups.
Cite:
Torgov V.
, Erenburg S.
, Bausk N.
, Stoyanov E.
, Kalchenko V.
, Varnek A.
, Wipff G.
The Structure of New Heterometallic Ru/M (M = Cu, Ni, Co, Zn) Complexes Investigated by Combined Spectroscopic and Modeling Studies
Journal of Molecular Structure. 2002. V.611. N1-3. P.131-138. DOI: 10.1016/S0022-2860(02)00059-5 WOS Scopus РИНЦ
The Structure of New Heterometallic Ru/M (M = Cu, Ni, Co, Zn) Complexes Investigated by Combined Spectroscopic and Modeling Studies
Journal of Molecular Structure. 2002. V.611. N1-3. P.131-138. DOI: 10.1016/S0022-2860(02)00059-5 WOS Scopus РИНЦ
Dates:
Submitted: | Dec 3, 2001 |
Accepted: | Feb 4, 2002 |
Published online: | Mar 6, 2002 |
Published print: | Jun 19, 2002 |
Identifiers:
Web of science | WOS:000176144400014 |
Scopus | 2-s2.0-0037134742 |
Elibrary | 13405699 |
Chemical Abstracts | 2002:336614 |
Chemical Abstracts (print) | 137:225695 |
OpenAlex | W2056916217 |