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Mechanism for Selective Oxidation of Ethanol over V-Ti Catalyst Conference attendances

Language Английский
Participant type Oral
Conference EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , ConferenceType.INTERNATIONAL_CONGRESS, Казань
Authors Kaichev Vasily Vasilievich 1 , Chesalov Yuriy Aleksandrovich 1 , Saraev Andrey Aleksandrovich 1 , Klyushin Alexander 2 , Knop-Gericke Axel 2 , Andrushkevich Tamara Vitalievna 1 , Bukhtiyarov Valerii Ivanovich 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS
2 Fritz Haber Institute of the Max Planck Society

Abstract: The selective oxidation of ethanol to acetaldehyde and acetic acid over a monolayer V2O5/TiO2 catalyst has been studied in situ using Fourier transform infrared spectroscopy and near ambient-pressure X-ray photoelectron spectroscopy. The data were complemented by temperature–programmed reaction spectroscopy and kinetic measurements in a flow reactor. Based on the obtained data the mechanism for the oxidation of ethanol over vanadia-titania catalysts is developed.
Cite: Каичев В.В. , Чесалов Ю.А. , Сараев А.А. , Клюшин А.Ю. , Knop-Gericke A. , Андрушкевич Т.В. , Бухтияров В.И.
Mechanism for Selective Oxidation of Ethanol over V-Ti Catalyst
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015