Effect of Nitrogen Doping of Carbon Supports for Hydrogen Production from Formic Acid Decomposition over Noble Metal Clusters and Atoms
Conference attendances
| Language |
Английский |
| Participant type |
Oral |
| Conference |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015
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ConferenceType.INTERNATIONAL_CONGRESS, Казань
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| Authors |
Bulushev Dmitri Aleksandrovich
1,2
, Zacharska Monika
2
, Podyacheva Olga Yurʹevna
1
, Jia Lijun
2
, Kibis Lidiya Sergeevna
1
, Boronin Andrei Ivanovich
1
, Shlyakhova Elena Valentinovna
3
, Bulusheva Lyubovʹ Gennadʹevna
3
, Guo Y.
2
, Chuvilin Andrej Leonidovich
4
, Beloshapkin Sergei Aleksandrovich
2
, Okotrub Aleksandr Vladimirovich
3
, Ramasse Quentin
5
, Bangert Ursel
2
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| Affiliations |
| 1 |
Boreskov Institute of Catalysis SB RAS
|
| 2 |
University of Limerick
|
| 3 |
Nikolaev Institute of Inorganic Chemistry SB RAS
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| 4 |
CIC nanoGUNE Consolider
|
| 5 |
Daresbury Laboratory
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Effects of N-doping of carbon nanofibers and mesoporous graphene like carbon were studied for hydrogen production by decomposition of formic acid over Pt, Pd and Ru clusters of less than 3 nm size. N-doping of the supports
(6-7 at.% N) provides a considerable increase of the formic acid decomposition rate (up to 10 times for Pt), selectivity to hydrogen (from 96.2 to 99.5% for Pt) and resistance to CO inhibition. This could be related to the presence of electron-deficient clusters and isolated atoms of metals stabilized by pyridinic nitrogen on the open edge graphene sites; these can dehydrogenate an intermediate adduct of formic acid with pyridinic nitrogen (>NH+HCOO-) to give hydrogen and carbon dioxide. The N doped Pd and Pt catalysts showed the highest activity in the hydrogen production.