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Mechanochemical Synthesis and Catalytic Properties of the Calcium Ferrite Ca2Fe2O5 Научная публикация

Общее Язык: Английский, Жанр: Статья (Full article),
Статус опубликования: Опубликована, Оригинальность: Переводная
Журнал Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Вых. Данные Год: 2002, Том: 43, Номер: 1, Страницы: 122-128 Страниц : 7 DOI: 10.1023/A:1014217716883
Авторы Isupova L.A. 1 , Tsybulya S.V. 1 , Kryukova G.N. 1 , Budneva A.A. 1 , Paukshtis E.A. 1 , Litvak G.S. 1 , Ivanov V.P. 1 , Kolomiichuk V.N. 1 , Pavlyukhin Y.T. 2 , Sadykov V.A. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2 Institute of Solid-State Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630128 Russia

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 99-03-32836

Реферат: The formation of the real structure of calcium ferrite prepared by the calcination of a mechanochemically activated hydroxide mixture at 600–1100°C was studied by X-ray diffraction analysis, electron microscopy, thermal analysis, Moessbauer spectroscopy, IR spectroscopy, small-angle X-ray scattering, and secondary-ion mass spectrometry. It was found that low-temperature calcium ferrite is an anion-modified oxide, in which the ordering of oxygen vacancies was incomplete. Regions with a disordered structure were detected on the surface of crystallites. As the calcination temperature was increased, the brownmillerite crystal structure was improved and the intercrystalline boundaries were formed and then annealed. At the surface, these processes were accompanied by a change in the predominant form of adsorbed NO from nitrosyl to dinitrosyl species. An increase in the specific catalytic activity of samples with calcination temperature can be associated with the perfection of the brownmillerite structure and with a change in the state of adsorption centers.
Библиографическая ссылка: Isupova L.A. , Tsybulya S.V. , Kryukova G.N. , Budneva A.A. , Paukshtis E.A. , Litvak G.S. , Ivanov V.P. , Kolomiichuk V.N. , Pavlyukhin Y.T. , Sadykov V.A.
Mechanochemical Synthesis and Catalytic Properties of the Calcium Ferrite Ca2Fe2O5
Kinetics and Catalysis. 2002. V.43. N1. P.122-128. DOI: 10.1023/A:1014217716883 WOS Scopus РИНЦ
Оригинальная версия: Исупова Л.А. , Цыбуля С.В. , Крюкова Г.Н. , Буднева А.А. , Паукштис Е.А. , Литвак Г.С. , Иванов В.П. , Коломийчук В.Н. , Павлюхин Ю.Т. , Садыков В.А.
Механохимический синтез и каталитические свойства феррита кальция - Ca2Fe2O5
Кинетика и катализ. 2002. Т.43. №1. С.132-139. РИНЦ
Даты:
Поступила в редакцию: 29 мар. 2000 г.
Опубликована в печати: 1 янв. 2002 г.
Идентификаторы:
Web of science WOS:000174318000019
Scopus 2-s2.0-0038575858
РИНЦ 13404190
Chemical Abstracts 2002:218850
Chemical Abstracts (print) 136:222247
Альметрики: