Reactivity of the Peroxo Complexes of Copper(II) Hydroxide
Научная публикация
| Общая информация |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584
, E-ISSN: 1608-3210
|
| Вых. Данные |
Год: 2003,
Том: 44,
Номер: 2,
Страницы: 211-220
Страниц
: 10
DOI:
10.1023/A:1023352412121
|
| Авторы |
Elizarova G.L.
1
,
Odegova G.V.
1
,
Matvienko L.G.
1
,
Talsi E.P.
1
,
Kolomiichuk V.N.
1
,
Parmon V.N.
1
|
| Организации |
| 1 |
Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia
|
|
In the interaction with H2O2 in an alkaline medium, Cu(OH)2 forms terminal Cu–OOH and bridging peroxo complexes with the μ-1,1 and μ-η2:η2 structures. It was found that the terminal peroxide is active in the reactions of H2O2 decomposition, diphenol oxidation, and nitrile conversion into acid amides. The promoting effect of ammonia on these reactions was found. A possible mechanism is discussed.