Catalytic Reaction Accompanied by Capillary Condensation, 3. Influence on Reaction Kinetics and Dynamics Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 1998, Том: 65, Номер: 2, Страницы: 321-329 Страниц : 9 DOI: 10.1007/BF02475271 | ||
Ключевые слова | Capillary condensation, Catalytic reaction, Dynamics, Kinetics | ||
Авторы |
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Организации |
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Реферат:
The influence of capillary condensation of reagents on the catalytic reaction kinetics and dynamics was studied. The hydrogenation of p-xylene over Pt/SiO2 was used as a model reaction. Two types of SiO2 were used (KCK-1 with large pores and KCM-5 with small pores). It was shown that capillary condensation could modify the kinetics and the transition regimes. The proposed mathematical model demonstrates good agreement with experimental results for both steady-state and dynamic regimes, including reaction rate—temperature hysteresis.
Библиографическая ссылка:
Bukhavtsova N.M.
, Ostrovskii N.M.
Catalytic Reaction Accompanied by Capillary Condensation, 3. Influence on Reaction Kinetics and Dynamics
Reaction Kinetics and Catalysis Letters. 1998. V.65. N2. P.321-329. DOI: 10.1007/BF02475271 WOS Scopus РИНЦ
Catalytic Reaction Accompanied by Capillary Condensation, 3. Influence on Reaction Kinetics and Dynamics
Reaction Kinetics and Catalysis Letters. 1998. V.65. N2. P.321-329. DOI: 10.1007/BF02475271 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 28 июн. 1997 г. |
Принята к публикации: | 7 окт. 1997 г. |
Опубликована в печати: | 1 нояб. 1998 г. |
Идентификаторы БД:
Web of science | WOS:000077523200018 |
Scopus | 2-s2.0-0000945652 |
РИНЦ | 13284780 |
Chemical Abstracts | 1999:284842 |
Chemical Abstracts (print) | 130:287600 |
OpenAlex | W1966615040 |