Methane Selective Oxidation into Syngas by the Lattice Oxygen in Ceria-Based Solid Electrolytes Promoted by Pt
Научная публикация
Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
Конференция |
7th Natural Gas Conversion Symposium
06-10 июн. 2004
,
Dalian
|
Сборник |
Natural Gas Conversion VII : Proceedings of the 7th Natural Gas Conversion Symposium, Dalian, China, 6-10 June 2004
Сборник,
Elsevier. 2004.
730 c. ISBN 9780444515995.
|
Журнал |
Studies in Surface Science and Catalysis
ISSN: 0167-2991
|
Вых. Данные |
Год: 2004,
Том: 147,
Номер: Natural Gas Conversion VII,
Страницы: 241-246
Страниц
: 6
DOI:
10.1016/S0167-2991(04)80058-2
|
Авторы |
Sadykov V.
1
,
Lunin V.
2
,
Kuznetsova T.
1
,
Alikina G.
1
,
Lukashevich A.
1
,
Potapova Yu.
1,6
,
Muzykantov V.
1
,
Veniaminov S.
1
,
Rogov V.
1
,
Kriventsov V.
1
,
Kochubei D.
1
,
Moroz E.
1
,
Zuzin D.
1
,
Zaikovskii V.
1
,
Kolomiichuk V.
1
,
Paukshtis E.
1
,
Burgina E.
1
,
Zyryanov V.
3
,
Neophytides S.
4
,
Kemnitz E.
5
|
Организации |
1 |
Boreskov Institute of Catalysis, Lavrentieva, 5, Novosibirsk, 630090, Russia
|
2 |
Chemical Department of Moscow State University, Moscow, Russia
|
3 |
Institute of Solid State Chemistry SB RAS Novosibirsk, Russia
|
4 |
Institute of Chemical Engineering, Patras, Greece
|
5 |
Institute for Chemistry, Humboldt- University, Berlin, Germany
|
6 |
Samsung Advanced Institute of Technology, Suwon, Republic of Korea
|
|
Информация о финансировании (4)
1
|
Президиум СО РАН
|
39
|
2
|
International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union
|
01-2162
|
3
|
Президиум РАН
|
8.17
|
4
|
International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union
|
IR-97-402
|
Nanocomposites based upon ceria doped by Zr, Zr+La or Sm with supported Pt nanoparticles efficiently convert methane into syngas by their lattice oxygen. In red-ox cycles with pure methane as reagent, the surface carbon build-up is observed, which is lower for Sm -doped samples possessing a higher surface and lattice oxygen mobility. When stoichiometric amounts of CO2 or H2O are present in the feed, the catalysts efficiently operate in methane steam and dry reforming at high space velocities without deactivation.