Thermodynamic Function Analogue for Reactions Proceeding without Interaction of Various Substances Научная публикация
Журнал |
Chemical Engineering Science
ISSN: 0009-2509 , E-ISSN: 1873-4405 |
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Вых. Данные | Год: 1986, Том: 41, Номер: 11, Страницы: 2739-2745 Страниц : 7 DOI: 10.1016/0009-2509(86)80005-7 | ||||
Ключевые слова | CARBON MONOXIDE - Oxidation; CATALYSIS - Mathematical Models; CATALYSTS - Platinum; CHEMICAL EQUIPMENT; THERMODYNAMICS - Mathematical Models | ||||
Авторы |
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Организации |
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Реферат:
A function similar to Lyapunov's function has been constructed for reactions with αAi→ ∑βjAj stages. This provides for the quasi-thermodynamics of the appropriate kinetic model, which implies steady-state uniqueness and global stability in the reaction polyhedron. The kinetic law generalizing the Marcelin-de Donder kinetics has been written for a separate stage. Explicit Lyapunov thermodynamic functions have been written for various conditions of the reaction proceeding in closed systems. The matrix of linear approximation close to equilibrium is expressed by means of the introduced scalar product. Particularly, the absence of damped oscillations as equilibrium is approached as shown.
Библиографическая ссылка:
Gorbanʹ A.N.
, Bykov V.I.
, Yablonskii G.S.
Thermodynamic Function Analogue for Reactions Proceeding without Interaction of Various Substances
Chemical Engineering Science. 1986. V.41. N11. P.2739-2745. DOI: 10.1016/0009-2509(86)80005-7 WOS Scopus РИНЦ
Thermodynamic Function Analogue for Reactions Proceeding without Interaction of Various Substances
Chemical Engineering Science. 1986. V.41. N11. P.2739-2745. DOI: 10.1016/0009-2509(86)80005-7 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 31 янв. 1984 г. |
Принята к публикации: | 13 янв. 1986 г. |
Опубликована в печати: | 1 июн. 1986 г. |
Опубликована online: | 5 окт. 2001 г. |
Идентификаторы БД:
Web of science | WOS:A1986E886200005 |
Scopus | 2-s2.0-0022920638 |
РИНЦ | 26590742 |
Chemical Abstracts | 1981:72199 |
Chemical Abstracts (print) | 94:72199 |
OpenAlex | W2024896645 |