The Effect of Adsorbate-Induced Surface Reconstruction on the Apparent Arrhenius Parameters for Desorption Научная публикация
Журнал |
Journal of Chemical Physics
ISSN: 0021-9606 , E-ISSN: 1089-7690 |
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Вых. Данные | Год: 1990, Том: 92, Номер: 6, Страницы: 3909-3916 Страниц : 8 DOI: 10.1063/1.457797 | ||
Авторы |
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Организации |
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Реферат:
The effect of adsorbate‐induced surface reconstruction on the apparent preexponential factor and activation energy for desorption is analyzed and discussed. The reconstruction is assumed to be a continuous order–disorder phase transition. The adsorbate‐induced changes in the surface are shown to result in a rather strong (of the order of 102) coverage dependence of the preexponential factor for desorption. The direction of the variation is in accordance with the compensation effect (the preexponential factor and the activation energy decrease with increasing coverage).
Библиографическая ссылка:
Myshlyavtsev A.V.
, Zhdanov V.P.
The Effect of Adsorbate-Induced Surface Reconstruction on the Apparent Arrhenius Parameters for Desorption
Journal of Chemical Physics. 1990. V.92. N6. P.3909-3916. DOI: 10.1063/1.457797 WOS Scopus РИНЦ
The Effect of Adsorbate-Induced Surface Reconstruction on the Apparent Arrhenius Parameters for Desorption
Journal of Chemical Physics. 1990. V.92. N6. P.3909-3916. DOI: 10.1063/1.457797 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 7 авг. 1989 г. |
Принята к публикации: | 6 нояб. 1989 г. |
Опубликована в печати: | 15 мар. 1990 г. |
Опубликована online: | 31 авг. 1998 г. |
Идентификаторы БД:
Web of science | WOS:A1990CU65800069 |
Scopus | 2-s2.0-0000502111 |
РИНЦ | 30810239 |
Chemical Abstracts | 1990:186436 |
Chemical Abstracts (print) | 112:186436 |
OpenAlex | W2020809721 |