Study on the Mechanism of Ethylene Oxidation by a Nitrite Complex of Palladium in Chloroform Medium
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102
|
| Вых. Данные |
Год: 1986,
Том: 37,
Номер: 2-3,
Страницы: 177-188
Страниц
: 12
DOI:
10.1016/0304-5102(86)85007-6
|
| Авторы |
Gusevskaya E.V.
1
,
Beck I.E.
1
,
Stepanov A.G.
1
,
Likholobov V.A.
1
,
Nekipelov V.M.
1
,
Yermakov Yu.I.
1
,
Zamaraev K.I.
1
|
| Организации |
|
A detailed mechanism of ethylene oxidation by a palladium nitrite complex Pd(NO2)Cl(CH3CN)2 in chloroform solution is studied using IR and 1H NMR spectroscopy. Kinetic and spectral data obtained indicate the formation of a number of intermediates. The structure and routes of decomposition of the intermediates to end products are suggested.