CO Oxidation to CO2 by Mo-V-P Heteropolyacid in the Presence of an Aqua Complex of Pd(II)
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736
, E-ISSN: 1588-2837
|
| Вых. Данные |
Год: 1986,
Том: 31,
Номер: 1,
Страницы: 113-120
Страниц
: 8
DOI:
10.1007/BF02062520
|
| Авторы |
Zhizhina E.G.
1
,
Kuznetsova L.I.
1
,
Matveev K.I.
1
|
| Организации |
| 1 |
Institute of Catalysis, Novosibirsk 630090, USSR
|
|
Kinetic oxidation of CO to CO2 by Mo−V−P heteropolyacid in the presence of an aqua complex of Pd(II) has been studied. The reaction is suggested to involve the participation of carbonyl complexes of Pd(I). It has been established that VO2+ ions formed in HPA dissociation inhibits the reaction.