Kinetic Studies of Methylmercaptan Production from Dimethyl Sulfide and H2S Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 1992, Том: 46, Номер: 1, Страницы: 187-192 Страниц : 6 DOI: 10.1007/BF02096696 | ||
Ключевые слова | Methyl; Physical Chemistry; Sulfide; Catalysis; Dimethyl; Alumina - Surface Properties; Catalysts - Activity; Chemical Reactions - Reaction Kinetics; Hydrogen Sulfide - Chemical Reactions | ||
Авторы |
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Организации |
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Реферат:
Kinetic regularities of methylmercaptan production from dimethyl sulfide and H2S in the presence of γ-Al2O3 have been studied under gradientless conditions. A stepwise reaction mechanism is suggested implying that the catalyst surface is methoxylated by methyl sulfide and then CH3O groups interact with H2S. The kinetic equation obtained describes fairly well this process on the nonhomogeneous catalyst surface.
Библиографическая ссылка:
Mashkin V.Y.
, Koshelev S.N.
Kinetic Studies of Methylmercaptan Production from Dimethyl Sulfide and H2S
Reaction Kinetics and Catalysis Letters. 1992. V.46. N1. P.187-192. DOI: 10.1007/BF02096696 WOS Scopus РИНЦ
Kinetic Studies of Methylmercaptan Production from Dimethyl Sulfide and H2S
Reaction Kinetics and Catalysis Letters. 1992. V.46. N1. P.187-192. DOI: 10.1007/BF02096696 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 11 мая 1991 г. |
Принята к публикации: | 25 июн. 1991 г. |
Опубликована в печати: | 1 янв. 1992 г. |
Идентификаторы БД:
Web of science | WOS:A1992HD87500028 |
Scopus | 2-s2.0-0026626638 |
РИНЦ | 31071662 |
Chemical Abstracts | 1992:151073 |
Chemical Abstracts (print) | 116:151073 |
OpenAlex | W2038511923 |