Kinetic Studies of Dimethyl Sulfide Synthesis from Methanol and H2S Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 1992, Том: 46, Номер: 2, Страницы: 263-269 Страниц : 7 DOI: 10.1007/BF02070944 | ||
Ключевые слова | Ether; Methanol; Physical Chemistry; Sulfide; Catalysis; Catalysis - Reaction Kinetics; Catalysts - Oxides; Mathematical Models; Methanol Hydrogen Sulfide | ||
Авторы |
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Организации |
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Реферат:
Kinetic regularities of dimethyl sulfide synthesis from methanol and H2S in the presence of WO3/Al2O3 have been studied under gradientless conditions. A stepwise mechanism of the reaction is suggested implying that methanol methoxylates the catalyst surface, the reaction of CH3O groups with H2S yields methylmercaptan and then dimethyl sulfide, whereas that with methanol produces dimethyl ether. The kinetic equations describe fairly well the process on inhomogeneous catalyst surface.
Библиографическая ссылка:
Mashkin V.Y.
, Kudenkov V.M.
Kinetic Studies of Dimethyl Sulfide Synthesis from Methanol and H2S
Reaction Kinetics and Catalysis Letters. 1992. V.46. N2. P.263-269. DOI: 10.1007/BF02070944 WOS Scopus РИНЦ
Kinetic Studies of Dimethyl Sulfide Synthesis from Methanol and H2S
Reaction Kinetics and Catalysis Letters. 1992. V.46. N2. P.263-269. DOI: 10.1007/BF02070944 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 21 авг. 1991 г. |
Принята к публикации: | 8 окт. 1991 г. |
Опубликована в печати: | 1 мар. 1992 г. |
Идентификаторы БД:
Web of science | WOS:A1992HM78000004 |
Scopus | 2-s2.0-0026832098 |
РИНЦ | 31072289 |
Chemical Abstracts | 1992:235032 |
Chemical Abstracts (print) | 116:235032 |
OpenAlex | W2038192541 |