Features of the Interaction of a CO + O2 Mixture with Silver under High Pressure Научная публикация
Журнал |
Surface Science
ISSN: 0039-6028 |
||
---|---|---|---|
Вых. Данные | Год: 1993, Том: 293, Номер: 1-2, Страницы: L826-L829 Страниц : 4 DOI: 10.1016/0039-6028(93)90229-D | ||
Ключевые слова | Carbon-monoxide, Oxygen-adsorption, Ag(111), Oxidation, Surface, Photoelectron, Ethylene, XPS, UPS | ||
Авторы |
|
||
Организации |
|
Реферат:
The interaction of CO + O2 reaction mixtures with polycrystalline silver has been studied by XPS and TPD. When the clean silver surface is exposed to a CO + O2 mixture, CO dissociates with the formation of carbon atoms. This process proceeds through the decomposition of surface carbonate formed during the interaction of CO2 as a product of CO oxidation with transient surface oxygen. The appearance of carbon atoms is accompanied by the accumulation of so-called “covalent” oxygen, taking an active part in ethylene epoxidation.
Библиографическая ссылка:
Bukhtiyarov V.I.
, Kondratenko V.A.
, Boronin A.I.
Features of the Interaction of a CO + O2 Mixture with Silver under High Pressure
Surface Science. 1993. V.293. N1-2. P.L826-L829. DOI: 10.1016/0039-6028(93)90229-D WOS Scopus РИНЦ
Features of the Interaction of a CO + O2 Mixture with Silver under High Pressure
Surface Science. 1993. V.293. N1-2. P.L826-L829. DOI: 10.1016/0039-6028(93)90229-D WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 15 дек. 1992 г. |
Принята к публикации: | 24 мая 1993 г. |
Опубликована в печати: | 10 авг. 1993 г. |
Опубликована online: | 30 авг. 2002 г. |
Идентификаторы БД:
Web of science | WOS:A1993LR49400002 |
Scopus | 2-s2.0-0027641320 |
РИНЦ | 31094375 |
Chemical Abstracts | 1993:547421 |
Chemical Abstracts (print) | 119:147421 |
OpenAlex | W3133571407 |