Photoinduced Electron Transfer Across Membranes Обзор
Сборник | Photoinduced Electron Transfer III Сборник, Springer. Berlin, Heidelberg.2005. 259 c. ISBN 978-3-540-53257-6. |
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Журнал |
Topics in Current Chemistry
ISSN: 0340-1022 , E-ISSN: 1436-5049 |
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Вых. Данные | Год: 1991, Том: 159, Страницы: 1-65 Страниц : 65 DOI: 10.1007/3-540-53257-9_1 | ||
Ключевые слова | Electron Transfer; Radical Cation; Electron Tunneling; Photoinduced Electron Transfer; Photoinduced Charge Separation | ||
Авторы |
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Организации |
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Реферат:
Vectorial photoinduced electron transfer (PET) across bilayer lipid and surfactant membranes provides a unique opportunity for the spatial separation of photochemically generated oxidants and reductants. In this chapter a review is given of the data on vectorial PET across the membranes of vesicles and planar bilayer membranes. The key steps that determine the efficiency of PET across membranes are discussed, i.e. (i) primary photochemical charge separation processes, (ii) secondary recombination reactions and (iii) electron transfer across membranes that provides stabilization of the charges generated in step (i). Step (iii) can be performed by three mechanisms: (1) via the diffusion of electron (or hole) carrier through the membrane, (2) via reactions of electron exchange between molecules located in different monolayers of a bilayer membrane and (3) via intramolecular electron transfer along bridging molecules, molecular wires and ultrafine semiconductor particles embedded into membranes. The possibility of conjugating PET across membranes with catalytic redox reactions is discussed with the emphasis on the water cleavage.
Библиографическая ссылка:
Lymar S.V.
, Parmon V.N.
, Zamaraev K.I.
Photoinduced Electron Transfer Across Membranes
В сборнике Photoinduced Electron Transfer III. – Springer., 1991. – C.1-65. – ISBN 978-3-540-53257-6. DOI: 10.1007/3-540-53257-9_1 WOS РИНЦ
Photoinduced Electron Transfer Across Membranes
В сборнике Photoinduced Electron Transfer III. – Springer., 1991. – C.1-65. – ISBN 978-3-540-53257-6. DOI: 10.1007/3-540-53257-9_1 WOS РИНЦ
Даты:
Опубликована online: | 27 мая 2005 г. |
Идентификаторы БД:
Web of science | WOS:A1991FZ31800001 |
РИНЦ | 19126146 |
Chemical Abstracts | 1991:643655 |
Chemical Abstracts (print) | 115:243655 |
OpenAlex | W2136664494 |