Adducts of β-Diketonato-Complexes of VO2+ and Cu2+, from ESR Data Научная публикация
Журнал |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Вых. Данные | Год: 1979, Том: 19, Номер: 4, Страницы: 570-575 Страниц : 6 DOI: 10.1007/BF00745683 | ||
Ключевые слова | Physical Chemistry; Inorganic Chemistry; Adduct | ||
Авторы |
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Организации |
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Реферат:
ESR has been used to study the adducts of VO(acac)2 and chelate compounds of Cu 2+ and VO 2+, where the chelate-forming ligand is acetylacetone, in which one of the methyl groups has been replaced by R=(-C(CH3) (n-C6H13)(OCH3)). It has been shown that the behavior of the substituted acetylacetonato-compound of copper in reactions with donor bases is similar to the behavior of Cu(acac) 2. The ESR spectra of the adducts of the substituted and nonsubstituted vanadyl acetylacetonates with n-butylphosphine shows AHFS at the phosphorus nucleus (A P~ 25 G), which is explained by assuming that the phsophine molecule shows planar coordination. From an analysis of the ESR parameters of the adducts of VO 2+ complexes with various bases and their relative stability it has been concluded that the planar coordination of the molecule of the base predominates in a number of adducts of vanadyl complexes with nitrogen and oxygen donors
Библиографическая ссылка:
Geraseva N.A.
, Shklyaev A.A.
, Zanina A.S.
, Anufrienko V.F.
Adducts of β-Diketonato-Complexes of VO2+ and Cu2+, from ESR Data
Journal of Structural Chemistry. 1979. V.19. N4. P.570-575. DOI: 10.1007/BF00745683 WOS Scopus РИНЦ
Adducts of β-Diketonato-Complexes of VO2+ and Cu2+, from ESR Data
Journal of Structural Chemistry. 1979. V.19. N4. P.570-575. DOI: 10.1007/BF00745683 WOS Scopus РИНЦ
Оригинальная версия:
Герасева Н.А.
, Шкляев А.А.
, Занина А.С.
, Ануфриенко В.Ф.
Аддукты β-дикетонатных комплексов VO2+ и Cu2+ по данным ЭПР
Журнал структурной химии. 1978. Т.19. №4. С.660-666. РИНЦ
Аддукты β-дикетонатных комплексов VO2+ и Cu2+ по данным ЭПР
Журнал структурной химии. 1978. Т.19. №4. С.660-666. РИНЦ
Даты:
Поступила в редакцию: | 28 окт. 1976 г. |
Опубликована в печати: | 1 июл. 1979 г. |
Идентификаторы БД:
Web of science | WOS:A1978GV85100013 |
Scopus | 2-s2.0-34250280048 |
РИНЦ | 29818465 |
OpenAlex | W2089848280 |
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Пока нет цитирований