INDO Study of the Interaction of Methanol with Molybdates Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 1978, Том: 9, Номер: 1, Страницы: 79-83 Страниц : 5 DOI: 10.1007/BF02070373 | ||||
Ключевые слова | Methanol; Physical Chemistry; Catalysis; Molybdate; Force Constant | ||||
Авторы |
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Организации |
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Реферат:
The energy of interaction between a methanol molecule and an MoO42− group of the Fe2(MoO4)3 and Ga2(MoO4)3 lattice, and the force constant of the C−H bond calculated by the INDO method show that the deformation of MoO42− tetrahedra leading to the displacement of Mo6+ to the edge attacked, increase the stabilizing contribution to the energy and decrease the C−H force constant. This effect is maximal at 1Mo−O≃2 Å.
Библиографическая ссылка:
Sutula V.D.
, Zeif A.P.
, Popov B.I.
, Vadash P.I.
INDO Study of the Interaction of Methanol with Molybdates
Reaction Kinetics and Catalysis Letters. 1978. V.9. N1. P.79-83. DOI: 10.1007/BF02070373 WOS Scopus РИНЦ
INDO Study of the Interaction of Methanol with Molybdates
Reaction Kinetics and Catalysis Letters. 1978. V.9. N1. P.79-83. DOI: 10.1007/BF02070373 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 19 июл. 1977 г. |
Принята к публикации: | 10 янв. 1978 г. |
Опубликована в печати: | 1 мар. 1978 г. |
Идентификаторы БД:
Web of science | WOS:A1978FX41200014 |
Scopus | 2-s2.0-34250275318 |
РИНЦ | 30924275 |
Chemical Abstracts | 1979:54344 |
Chemical Abstracts (print) | 90:54344 |
OpenAlex | W1990118571 |