On the Role of σ- and π-Allyl Complexes in the Oxidation of Propylene to Acrolein Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 1975, Том: 2, Номер: 1-2, Страницы: 163-170 Страниц : 8 DOI: 10.1007/BF02060967 | ||
Ключевые слова | Oxidation; Physical Chemistry; Nickel; SiO2; Bromide | ||
Авторы |
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Организации |
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Реферат:
The conversions of the σ- and π-allyl complexes of propylene formed (1) upon the adsorption of propylene and allyl bromide on an oxide catalyst surface, and (2) upon interacting bis(π-allyl)nickel and tetrakis(π-allyl)-molybdenum with a SiO2 surface have been studied by thermodesorption techniques. From the results it has been concluded that symmetric π-allyl and asymmetric σ-allyl complexes of propylene may participate in the formation of acrolein.
Библиографическая ссылка:
Mikhalchenko V.G.
, Davydov A.A.
, Budneva A.A.
, Kuznetsov B.N.
, Sokolovskii V.D.
On the Role of σ- and π-Allyl Complexes in the Oxidation of Propylene to Acrolein
Reaction Kinetics and Catalysis Letters. 1975. V.2. N1-2. P.163-170. DOI: 10.1007/BF02060967 WOS Scopus РИНЦ
On the Role of σ- and π-Allyl Complexes in the Oxidation of Propylene to Acrolein
Reaction Kinetics and Catalysis Letters. 1975. V.2. N1-2. P.163-170. DOI: 10.1007/BF02060967 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 28 мар. 1974 г. |
Опубликована в печати: | 1 мар. 1975 г. |
Идентификаторы БД:
Web of science | WOS:A1975W268400022 |
Scopus | 2-s2.0-34250406481 |
РИНЦ | 30836623 |
Chemical Abstracts | 1975:478161 |
Chemical Abstracts (print) | 83:78161 |
OpenAlex | W2088922317 |