A Homochiral Metal-Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
| Журнал |
Angewandte Chemie - International Edition
ISSN: 1433-7851
, E-ISSN: 1521-3773
|
| Вых. Данные |
Год: 2006,
Том: 45,
Номер: 6,
Страницы: 916-920
Страниц
: 5
DOI:
10.1002/anie.200503023
|
| Ключевые слова |
Chirality, Heterogeneous catalysis, Metal-organic frameworks, Microporous materials, Sorption |
| Авторы |
Dybtsev Danil N.
1,2
,
Nuzhdin Alexey L.
3
,
Chun Hyungphil
1
,
Bryliakov Konstantin P.
3
,
Talsi Evgeniy P.
3
,
Fedin Vladimir P.
2
,
Kim Kimoon
1
|
| Организации |
| 1 |
National Creative Research Initiative Center for Smart Supramolecules and Department of Chemistry, Division of Molecular and Life Sciences, Pohang University of Science and Technology, San 31 Hyojadong, Pohang 790-784 (Republic of Korea)
|
| 2 |
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Pr. Lavrentieva 3, Novosibirsk 630090 (Russia)
|
| 3 |
Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Lavrentieva 5, Novosibirsk 630090 (Russia)
|
|
Информация о финансировании (2)
|
1
|
Российский фонд фундаментальных исследований
|
03-03-32009
|
|
2
|
Совет по грантам Президента Российской Федерации
|
МК-3842.2004.3
|
A handy approach: A new synthetic approach starting from readily available chemicals successfully produces a robust homochiral metal–organic microporous framework. The material exhibits size- and enantioselective guest-sorption properties (see picture), as well as remarkable catalytic activity with size- and chemoselectivity, and high conversion in the oxidation of thioethers to sulfoxides.