Potentials of Gas Chromatography in the Determination of Reaction Products in the Catalytic Oxidation of Ammonia
to Nitrogen(II) Oxide
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
| Конференция |
Annual Session of the Scientific-Council-on-Analytical-Chemistry of the Russian-Academy-of-Sciences
12-17 нояб. 2006
,
Moscow,
|
| Журнал |
Journal of Analytical Chemistry
ISSN: 1061-9348
, E-ISSN: 1608-3199
|
| Вых. Данные |
Год: 2007,
Том: 62,
Номер: 12,
Страницы: 1170-1175
Страниц
: 6
DOI:
10.1134/S1061934807120131
|
| Авторы |
Zheivot V.I.
1
,
Nikoro T.A.
1
,
Krivoruchko V.N.
1
,
Panina L.I.
1
,
Pinaeva L.G.
1
,
Isupova L.A.
1
|
| Организации |
| 1 |
Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090 Russia
|
|
Peculiarities of the determination of nitrogen oxides and ammonia in the reaction products of ammonia oxidation are studied by gas chromatography. Particular attention was paid to the sampling problem. It is shown that in the course of the transportation of samples containing nitrogen(II) oxide and oxygen, the oxidation of nitrogen(II) oxide to nitrogen(IV) oxide takes place in the vapor phase. The conditions were found for suppressing or even eliminating the gas-phase reaction of NO oxidation to NO2. A procedure for the gas-chromatographic analysis of the reaction products in the catalytic oxidation of ammonia is proposed using several samples and packed columns, including the determination of NO with respect to NO2 formed in the gas-phase oxidation of NO.