Kinetic Explosion and Bistability in Adsorption and Reaction of Acetic Acid on Pd(110) Научная публикация
Журнал |
PCCP: Physical Chemistry Chemical Physics
ISSN: 1463-9076 , E-ISSN: 1463-9084 |
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Вых. Данные | Год: 2007, Том: 9, Номер: 42, Страницы: 5700-5703 Страниц : 4 DOI: 10.1039/b709384e | ||||
Ключевые слова | VINYL-ACETATE SYNTHESIS; AUTOCATALYTIC DECOMPOSITION; SURFACE EXPLOSIONS; CO OXIDATION; Rh CRYSTALS; CATALYST; Pd; Au; MECHANISM; ETHYLENE | ||||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | Engineering and Physical Sciences Research Council | |
2 | BP Chemicals Limited, Research Laboratory |
Реферат:
The adsorption and reaction of acetic acid with Pd(110) have been studied using thermal molecular beam reaction measurements and temperature-programmed desorption. Acetic acid adsorption results in the formation of acetate species which decompose to produce coincident CO2 and H2 desorption from the surface. C is deposited on the surface from the dehydrogenation of the methyl group. In combination, these steps are found to exhibit unusual kinetics including (i) a “surface explosion” during heating and (ii) bistability in the reaction profile for heating and cooling curves. This is the first report of such behaviour for a complex system during in situ reaction.
Библиографическая ссылка:
Bowker M.
, Morgan C.
, Zhdanov V.P.
Kinetic Explosion and Bistability in Adsorption and Reaction of Acetic Acid on Pd(110)
PCCP: Physical Chemistry Chemical Physics. 2007. V.9. N42. P.5700-5703. DOI: 10.1039/b709384e WOS Scopus РИНЦ
Kinetic Explosion and Bistability in Adsorption and Reaction of Acetic Acid on Pd(110)
PCCP: Physical Chemistry Chemical Physics. 2007. V.9. N42. P.5700-5703. DOI: 10.1039/b709384e WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 20 июн. 2007 г. |
Принята к публикации: | 3 сент. 2007 г. |
Опубликована online: | 13 сент. 2007 г. |
Идентификаторы БД:
Web of science | WOS:000250399500010 |
Scopus | 2-s2.0-35449002411 |
РИНЦ | 13547753 |
Chemical Abstracts | 2007:1203019 |
Chemical Abstracts (print) | 147:548853 |
OpenAlex | W2158768135 |