Scandia-Stabilized Zirconia: Effect of Dopants on Surface/Grain Boundary Segregation and Transport Properties | Sciact - CRIS-система Института катализа

Scandia-Stabilized Zirconia: Effect of Dopants on Surface/Grain Boundary Segregation and Transport Properties Научная публикация

Общее

Язык: Английский, Жанр: Статья (Full article),
Статус опубликования: Опубликована, Оригинальность: Оригинальная

Конференция

2006 MRS Fall Meeting: Symposium AA - Solid-State Ionics-2006
27 нояб. - 1 дек. 2006 , Boston, MA

Сборник

Solid-State Ionics-2006 Symposium (2006 MRS Fall Meeting)
Сборник, 2007. ISBN 978-1-55899-929-9.

Журнал

Materials Research Society Symposium Proceedings
ISSN: 0272-9172

Вых. Данные

Год: 2006, Том: 972, Страницы: 155-161 Страниц : 7 DOI: 10.1557/PROC-0972-AA10-05

Авторы

Smirnova A. ¹ , Sadykov V. ² , Muzykantov V. ³ , Mezentseva N. ³ , Ivanov V. ³ , Zaikovskii V. ³ , Ishchenko A. ³ , Sammes N. ⁴ , Vasylyev O. ⁵ , Kilner J. ⁶ , Irvine J. ⁷ , Vereschak V. ⁸ , Kosacki I. ⁹ , Uvarov N. ¹⁰ , Zyryanov V. ¹⁰

Организации

1	Chemistry, Materials, and Biomolecular Engineering, UCONN, Storrs, CT, 06269
2	Boreskov Institute of Catalysis, Novosibirsk, 630090, Russian Federation
3	Boreskov Institute of Catalysis, 5 Pr. Ak. Lavrent'eva, Novosibirsk, 630090, Russian Federation
4	Mechanical Engineering, UCONN, Storrs, CT, 06269
5	Department of Physics of Strength and Plasticity, Institute for problems of Materials Science, Kyiv, 03680, Ukraine
6	Department of Materials, Imperial College, London, SW72AZ, United Kingdom
7	School of Chemistry, University of St. Andrews, Fife, KY169ST, United Kingdom
8	Ukrainian State Chemical Technology University, Dnepropetrovsk, 49005, Ukraine
9	Shell, Houston, TX, 77002
10	Institute of Solid State Chemistry and Mechanochemistry SB RAS, Novosibirsk, 630090, Russian Federation

Информация о финансировании (2)

1	Президиум СО РАН	95
2	North Atlantic Treaty Organization	SfP-980878

The nanocrystalline samples of 10wt.%Scandia stabilized Zirconia (10ScSZ) and 1wt.%Ceria doped ScSZ (1Ce10ScSZ) prepared via co-precipitation route were characterized and compared to commercially available samples regarding their transport properties and electrical conductivity. The results of oxygen isotope experiments show that for Zirconia-based electrolytes, the rate of heteroexchange is lower than that for Samaria-doped Ceria. The results of Secondary Ions Mass Spectrometry (SIMS) indicate that all admixed components are present both in the surface layer and the bulk of the studied samples with pronounced segregation on the grain boundary. The highest total conductivity is observed for DKKK sample. In the range of 600-400°C the highest conductivity observed for synthesized nanocrystalline 1Ce10ScSZ sample is explained by the effect of segregated Scandia doped Ceria surface layers.

Smirnova A. , Sadykov V. , Muzykantov V. , Mezentseva N. , Ivanov V. , Zaikovskii V. , Ishchenko A. , Sammes N. , Vasylyev O. , Kilner J. , Irvine J. , Vereschak V. , Kosacki I. , Uvarov N. , Zyryanov V.
Scandia-Stabilized Zirconia: Effect of Dopants on Surface/Grain Boundary Segregation and Transport Properties
В сборнике Solid-State Ionics-2006 Symposium (2006 MRS Fall Meeting). 2006. – C.155-161. – ISBN 978-1-55899-929-9. DOI: 10.1557/PROC-0972-AA10-05 Scopus РИНЦ WOS AN: 2007:489365 CAN: 147:106539

Опубликована в печати:	1 янв. 2006 г.
Опубликована online:	26 февр. 2011 г.

Chemical Abstracts	2007:489365
Chemical Abstracts (print)	147:106539
Scopus	2-s2.0-34250903517
РИНЦ	15049373
Web of science	WOS:000246435400021