One-Step Chemical Vapor Deposition Synthesis and Supercapacitor Performance of Nitrogen-Doped Porous Carbon-Carbon Nanotube Hybrids
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Beilstein Journal of Nanotechnology
ISSN: 2190-4286
|
| Вых. Данные |
Год: 2017,
Том: 8,
Номер: 1,
Страницы: 2669-2679
Страниц
: 11
DOI:
10.3762/bjnano.8.267
|
| Ключевые слова |
Bimetallic catalyst, Eectrochemical impedance spectroscopy, N-doped carbon, Porous carbon-carbon nanotube hybrid, Supercapacitor |
| Авторы |
Lobiak Egor V.
1
,
Bulusheva Lyubov G.
1,2
,
Fedorovskaya Ekaterina O.
1,2
,
Shubin Yury V.
1,2
,
Plyusnin Pavel E.
1,2
,
Lonchambon Pierre
3
,
Senkovskiy Boris V.
4,5
,
Ismagilov Zinfer R.
6,7
,
Flahaut Emmanuel
3
,
Okotrub Alexander V.
1,2
|
| Организации |
| 1 |
Nikolaev Institute of Inorganic Chemistry, SB RAS, 630090 Novosibirsk, Russia
|
| 2 |
Novosibirsk State University, 630090 Novosibirsk, Russia
|
| 3 |
CNRS, Institut Carnot Cirimat, F-31062 Toulouse, France
|
| 4 |
St. Petersburg State University, 7-9, Universitetskaya Nab., St. Petersburg 199034, Russia
|
| 5 |
II Physikalisches Institut, Universität zu Köln, Zülpicher Straße 77, 50937 Köln, Germany
|
| 6 |
Boreskov Institute of Catalysis, SB RAS, 630090 Novosibirsk, Russia
|
| 7 |
Institute of Coal Chemistry and Materials Science FRC CCC SB RAS, Kemerovo 650000, Russia
|
|
Информация о финансировании (4)
|
1
|
Российский фонд фундаментальных исследований
|
16-53-150003
|
|
2
|
European Commission
|
612577 FP7-PEOPLE-2013-IRSES
|
|
3
|
Российский фонд фундаментальных исследований
|
15-33-50685
|
|
4
|
Centre national de la recherche scientifique
|
1023
|
Novel nitrogen-doped carbon hybrid materials consisting of multiwalled nanotubes and porous graphitic layers have been produced by chemical vapor deposition over magnesium-oxide-supported metal catalysts. CNx nanotubes were grown on Co/Mo, Ni/Mo, or Fe/Mo alloy nanoparticles, and MgO grains served as a template for the porous carbon. The simultaneous formation of morphologically different carbon structures was due to the slow activation of catalysts for the nanotube growth in a carbon-containing gas environment. An analysis of the obtained products by means of transmission electron microscopy, thermogravimetry and X-ray photoelectron spectroscopy methods revealed that the catalyst's composition influences the nanotube/porous carbon ratio and concentration of incorporated nitrogen. The hybrid materials were tested as electrodes in a 1M H2SO4 electrolyte and the best performance was found for a nitrogen-enriched material produced using the Fe/Mo catalyst. From the electrochemical impedance spectroscopy data, it was concluded that the nitrogen doping reduces the resistance at the carbon surface/electrolyte interface and the nanotubes permeating the porous carbon provide fast charge transport in the cell.