Formation of Active Sites of Carbon Nanofibers Growth in Self-Organizing Ni−Pd Catalyst during Hydrogen-Assisted Decomposition of 1,2-Dichloroethane
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Конференция |
4th International Conference of Chemical Engineering & Industrial Biotechnology
01-02 авг. 2018
,
Kuala Lumpur
|
| Журнал |
Industrial and Engineering Chemistry Research
ISSN: 0888-5885
, E-ISSN: 1520-5045
|
| Вых. Данные |
Год: 2019,
Том: 58,
Номер: 2,
Страницы: 685-694
Страниц
: 10
DOI:
10.1021/acs.iecr.8b02186
|
| Ключевые слова |
Metal Dusting; Ni-Pd Alloys; Self-Organizing Catalyst; CCVD; 1,2-Dichloroethane; Carbon Filaments; Segmental Structure |
| Авторы |
Bauman Yurii I.
1
,
Mishakov Ilya V.
1,2
,
Rudneva Yulia V.
3
,
Plyusnin Pavel E.
3,4
,
Shubin Yury V.
3,4
,
Korneev Denis V.
5
,
Vedyagin Aleksey A.
1,2
|
| Организации |
| 1 |
Boreskov Institute of Catalysis SB RAS, pr. Ac. Lavrentieva 5, Novosibirsk 630090, Russian Federation
|
| 2 |
National Research Tomsk Polytechnic University, Lenin Avenue 30, Tomsk 634050, Russian Federation
|
| 3 |
Nikolaev Institute of Inorganic Chemistry SB RAS, pr. Ac. Lavrentieva 3, Novosibirsk 630090, Russian Federation
|
| 4 |
Novosibirsk State University, Pirogova straße 2, Novosibirsk 630090, Russian Federation
|
| 5 |
Monash University, Melbourne, Victoria 3800, Australia
|
|
Информация о финансировании (2)
|
1
|
Российский фонд фундаментальных исследований
|
16-33-60074
|
|
2
|
Федеральное агентство научных организаций России
|
0303-2016-0002
|
The Ni−Pd alloys synthesized by the coprecipitation method were studied as precursors for the self-organizing particles catalyzing the growth of carbon nanofibers. The addition of palladium was found to enhance both the activity, stability, and productivity of the catalyst in the hydrogen-assisted decomposition of 1,2-dichloroethane. The evolution of reflex (331) for the 95Ni−5Pd sample treated under the reaction conditions has revealed the formation of the interstitial solid solution phase NixPd1−xCδ. According to data of scanning electron microscopy, the formation of separated particles active in carbon growth takes place by 18th minute of exposure with the reaction mixture. After 60 min of interaction the bulk Ni−Pd alloy undergoes complete disintegration with formation of dispersed active centers sized in a range of 0.4−0.6 μm. The elemental mapping of the formed particles showed that palladium is uniformly distributed within the bulk of active particles. The obtained carbon product is represented by prolonged carbon fibers with segmental structure.