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Production of Substituted Anthraquinones via Diene Synthesis in the Presence of Solution of Mo-V-P Heteropoly Acid as Bifunctional Catalyst Тезисы доклада

Общее Язык: Английский, Жанр: Тезисы доклада (Meeting Abstracts),
Статус опубликования: Опубликована, Оригинальность: Оригинальная
Конференция EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 авг. - 4 сент. 2015 , Казань
Сборник EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Сборник, Boreskov Institute of Catalysis. Novosibirsk.2015. 2184 c. ISBN 9785906376107. РИНЦ
Вых. Данные Год: 2015, Страницы: 1444-1445 Страниц : 2
Авторы Gogin L.L. , Zhizhina E.G. , Pai Z.P.
Организации
1 Институт катализа им. Г.К. Борескова СО РАН

Реферат: 9,10-Anthraquinone and its derivatives are the valuable products of organic synthesis. We developed one-pot processes for the preparation of substituted anthraquinones via diene synthesis in the presence of heteropoly acid H17P3Mo16V10O89 (HPA-10) solution as a bifunctional catalyst, i.e., acidic catalyst for diene synthesis and catalyst for the oxidation of the obtained adduct. In the present study, experimental data were obtained for two one-pot processes: 1) 2-methylanthraquinone (2-MAQ) synthesis from naphthoquinone (NQ) and isoprene; 2) 2,3-dimethylanthraquinone (2,3-ДМАQ) synthesis from NQ and 2,3-dimethyl-butadiene. We investigated the possibility of multicycle catalyst performance. After the desired reaction, the HPA-10 solution was rapidly regenerated in separate stage and reused. Various methods for regeneration of the catalyst were alternated.
Библиографическая ссылка: Gogin L.L. , Zhizhina E.G. , Pai Z.P.
Production of Substituted Anthraquinones via Diene Synthesis in the Presence of Solution of Mo-V-P Heteropoly Acid as Bifunctional Catalyst
В сборнике EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – Boreskov Institute of Catalysis., 2015. – C.1444-1445. – ISBN 9785906376107.
Идентификаторы: Нет идентификаторов