State and the Catalytic Properties of Cu/ZSM-5 in Selective NO Reduction with Propane
Тезисы доклада
| Общее |
Язык:
Английский,
Жанр:
Тезисы доклада (Meeting Abstracts),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
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| Конференция |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 авг. - 4 сент. 2015
,
Казань
|
| Сборник |
EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Сборник,
Boreskov Institute of Catalysis. Novosibirsk.2015.
2184 c. ISBN 9785906376107.
РИНЦ
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| Вых. Данные |
Год: 2015,
Страницы: 618-619
Страниц
: 2
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| Авторы |
Shutilov R.
1
,
Zenkovets G.
1
,
Gavrilov V.
1
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| Организации |
| 1 |
Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
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Информация о финансировании (1)
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1
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Российский фонд фундаментальных исследований
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14-03-31372
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Catalytic properties of the Cu/ZSM-5 catalyst prepared by ion exchange of the HZSM-5 with aqueous ammonia solution of copper nitrate can be tuned by varying the nature of copper precursor (CC I or CC III). These factors have a significant effect on the copper species located on the surface of zeolite. In the SCR of NO with propane the highest reaction rate per gram of Cu attainable on the catalyst prepared from CC I. This due to the optimum size of Cu2+ oxide clusters, which ensures that a large proportion of the active component is have an optimum degree of covalence for the given process involved in the reaction and the copper–oxygen bonds.