Solvation Shell of Platinum Complexes in Solutions According to EXAFS Data
Тезисы доклада
| Общее |
Язык:
Английский,
Жанр:
Тезисы доклада (Meeting Abstracts),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
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| Конференция |
XII European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” (EuropaCat-XII)
30 авг. - 4 сент. 2015
,
Казань
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| Сборник |
EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Сборник,
Boreskov Institute of Catalysis. Novosibirsk.2015.
2184 c. ISBN 9785906376107.
РИНЦ
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| Вых. Данные |
Год: 2015,
Страницы: 457-458
Страниц
: 2
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| Авторы |
Kanazhevskiy V.
1
,
Chesalov Yu.
1
,
Kochubey D.
1
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| Организации |
| 1 |
Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
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|
Using EXAFS and vibrational spectroscopy a tightly bound solvation shell of H2PtCl6 in DMSO and water solutions is established. The shell contains H3O+, H5O2+ and DMSO molecules, depending on the solvent type. EXAFS suggests
O-atoms of the shell are located at a distance of 3.7-4.4 Å from Pt. Complexes' structure was studied in wide concentration range DMSO and water solutions. The complexes are mononuclear and unhydrolyzed. Combining via the shell is possible