Highly Stable Single-Atom Catalyst with Ionic Pd Active Sites Supported on N-Doped Carbon Nanotubes for Formic Acid Decomposition
Краткое сообщение
| Общее |
Язык:
Английский,
Жанр:
Краткое сообщение (Short communication),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
ChemSusChem
ISSN: 1864-5631
, E-ISSN: 1864-564X
|
| Вых. Данные |
Год: 2018,
Том: 11,
Номер: 21,
Страницы: 3724-3727
Страниц
: 4
DOI:
10.1002/cssc.201801679
|
| Ключевые слова |
single-atom catalyst; carbon nanotubes; nitrogen doping; palladium; formic acid |
| Авторы |
Podyacheva Olga Y.
1,2
,
Bulushev Dmitri A.
1,2
,
Suboch Arina N.
1
,
Svintsitskiy Dmitry A.
1,2
,
Lisitsyn Alexander S.
1
,
Modin Evgeny
3
,
Chuvilin Andrey
3,4
,
Gerasimov Evgeny Y.
1,2
,
Sobolev Vladimir I.
1
,
Parmon Valentin N.
1,2
|
| Организации |
| 1 |
Boreskov Institute of Catalysis SB RAS, Pr. Lavrentieva, 5, Novosibirsk, 630090 (Russia)
|
| 2 |
Novosibirsk State University, Pirogova 2, Novosibirsk, 630090 (Russia)
|
| 3 |
CIC nanoGUNE, Donostia - San Sebastian 20018 (Spain)
|
| 4 |
Ikerbasque, Basque Foundation for Science, Bilbao 48013 (Spain)
|
|
Информация о финансировании (2)
|
1
|
Российский научный фонд
|
17-73-30032
|
|
2
|
Ministerio de Economía y Empresa
|
MDM-2016-0618
|
Single-atom catalysts with ionic Pd active sites on nitrogen-doped carbon nanotubes have been synthesized with
palladium content of 0.2-0.5 wt.%. Unexpectedly high stability of these Pd sites up to 500 C in a hydrogen atmosphere was found and explained by coordination of the Pd ions by nitrogen-containing fragments of graphene layers. These active sites showed a high rate of gas-phase formic acid decomposition yielding hydrogen. An increase in Pd content was accompanied by the formation of metallic nanoparticles with a size of 1.2-1.4 nm and by a decrease in the
catalyst activity. The revealed high stability of the single-atom Pd sites opens the possibilities for using such catalysts in high temperature reactions.