Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2′-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of C–H Compounds
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Inorganic Chemistry
ISSN: 0020-1669
, E-ISSN: 1520-510X
|
| Вых. Данные |
Год: 2017,
Том: 57,
Номер: 1,
Страницы: 528-534
Страниц
: 7
DOI:
10.1021/acs.inorgchem.7b02881
|
| Ключевые слова |
CLUSTER ORGANIC FRAMEWORKS; METAL-METAL COOPERATIVITY; FISCHER-TROPSCH SYNTHESIS; COPPER(II) SILSESQUIOXANES; ALKANE OXIDATION; BENZYL ALCOHOLS; BORYLATION; PEROXIDES; AMIDATION; CAGES |
| Авторы |
Bilyachenko Alexey N.
1,2
,
Khrustalev Victor N.
2
,
Zubavichus Yan V.
3
,
Shul’pina Lidia S.
1
,
Kulakova Alena N.
1,2
,
Bantrei Xavier
4
,
Lamaty Fredéric
4
,
Levitsky Mikhail M.
1
,
Gutsul Evgeniy I.
1
,
Shubina Elena S.
1
,
Shul’pin Georgiy B.
4,5,6
|
| Организации |
| 1 |
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
|
| 2 |
Peoples’ Friendship University of Russia (RUDN University)
|
| 3 |
National Research Center “Kurchatov Institute”
|
| 4 |
Institut des Biomolecules Max Mousseron (IBMM), UMR 5247, CNRS, Universite ́ ́de Montpellier ENSCM
|
| 5 |
Semenov Institute of Chemical Physics, Russian Academy of Sciences
|
| 6 |
Plekhanov Russian University of Economics, Stremyannyi pereulok, dom 36, Moscow 117997, Russia
|
|
Информация о финансировании (7)
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1
|
Министерство образования и науки Российской Федерации
|
|
|
2
|
Российский фонд фундаментальных исследований
|
16-03-00609 (АААА-А15-115123110094-2)
|
|
3
|
Российский фонд фундаментальных исследований
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16-03-00254 (АААА-А16-116020350251-6)
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4
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Российский фонд фундаментальных исследований
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16-53-150008 (АААА-А16-116031110130-4)
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5
|
Посольство Франции в России
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6
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Centre national de la recherche scientifique
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7
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Российский фонд фундаментальных исследований
|
16-29-05180 (АААА-А16-116031110127-4)
|
A new representative of an unusual family of metallagermaniumsesquioxanes, namely the heterometallic cagelike phenylgermsesquioxane (PhGeO2)12Cu2Fe5(O)OH(PhGe)2O5(bipy)2 (2), was synthesized and structurally characterized. Fe(III) ions of the complex are coordinated by oxa ligands: (i) cyclic (PhGeO2)12 and acyclic (Ph2Ge2O5) germoxanolates and (ii) O2– and (iii) HO– moieties. In turn, Cu(II) ions are coordinated by both oxa (germoxanolates) and aza ligands (2,2′-bipyridines). This “hetero-type” of ligation gives in sum an attractive pagoda-like molecular architecture of the complex 2. Product 2 showed a high catalytic activity in the oxidation of alkanes to the corresponding alkyl hydroperoxides (in yields up to 30%) and alcohols (in yields up to 100%) and in the oxidative formation of benzamides from alcohols (catalyst loading down to 0.4 mol % in Cu/Fe).